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Hartwig, John

TitleChemist Senior Faculty SE
InstitutionLawrence Berkeley National Lab
DepartmentChemical Sciences
Address1 Cyclotron Road
Berkeley CA 94720
Phone510/642-2038
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    Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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    1. Wang JY, Strom AE, Hartwig J. Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia. J Am Chem Soc. 2018 May 31. PMID: 29852736.
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    2. Su B, Hartwig J. Ir-Catalyzed, Silyl-Directed, peri-Borylation of C-H Bonds in Fused Polycyclic Arenes and Heteroarenes. Angew Chem Int Ed Engl. 2018 May 20. PMID: 29779224.
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    3. Peacock DM, Jiang Q, Hanley PS, Cundari TR, Hartwig J. Reductive Elimination from Phosphine-Ligated Alkylpalladium(II) Amido Complexes To Form sp3 Carbon-Nitrogen Bonds. J Am Chem Soc. 2018 Apr 11; 140(14):4893-4904. PMID: 29537835.
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    4. Karimov RR, Hartwig J. Transition-Metal-Catalyzed Selective Functionalization of C(sp3 )-H Bonds in Natural Products. Angew Chem Int Ed Engl. 2018 Apr 09; 57(16):4234-4241. PMID: 29228463.
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    5. Karmel C, Li B, Hartwig J. Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols. J Am Chem Soc. 2018 Jan 31; 140(4):1460-1470. PMID: 29293327.
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    6. Bunescu A, Butcher TW, Hartwig J. Traceless Silylation of ß-C(sp3)-H Bonds of Alcohols via Perfluorinated Acetals. J Am Chem Soc. 2018 Jan 31; 140(4):1502-1507. PMID: 29283571.
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    7. Jiang X, Boehm P, Hartwig J. Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis. J Am Chem Soc. 2018 Jan 17. PMID: 29319306.
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    8. Giri R, Brusoe A, Troshin K, Wang JY, Font M, Hartwig J. Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands: Evidence for the Reaction of Iodoarenes with Ligated Anionic CuI Intermediates. J Am Chem Soc. 2018 Jan 17; 140(2):793-806. PMID: 29224350.
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    9. Saper NI, Hartwig J. Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands. J Am Chem Soc. 2017 Dec 06; 139(48):17667-17676. PMID: 29116776.
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    10. Arlow SI, Hartwig J. Synthesis, Characterization, and Reactivity of Palladium Fluoroenolate Complexes. J Am Chem Soc. 2017 11 15; 139(45):16088-16091. PMID: 29077395.
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    11. Xi Y, Hartwig J. Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes. J Am Chem Soc. 2017 Sep 13; 139(36):12758-12772. PMID: 28787137.
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    12. Su B, Hartwig J. Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C-H Bonds. J Am Chem Soc. 2017 Sep 06; 139(35):12137-12140. PMID: 28820264.
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    13. Hill CK, Hartwig J. Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation. Nat Chem. 2017 Dec; 9(12):1213-1221. PMID: 29168493.
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    14. Bunescu A, Lee S, Li Q, Hartwig J. Catalytic Hydroxylation of Polyethylenes. ACS Cent Sci. 2017 Aug 23; 3(8):895-903. PMID: 28852704.
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    15. Troshin K, Hartwig J. Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions. Science. 2017 07 14; 357(6347):175-181. PMID: 28706066.
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    16. Jiang X, Hartwig J. Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates. Angew Chem Int Ed Engl. 2017 Jul 17; 56(30):8887-8891. PMID: 28597600.
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    17. Key HM, Dydio P, Liu Z, Rha JY, Nazarenko A, Seyedkazemi V, Clark DS, Hartwig J. Beyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes. ACS Cent Sci. 2017 Apr 26; 3(4):302-308. PMID: 28470047.
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    18. Lee T, Hartwig J. Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds. J Am Chem Soc. 2017 04 05; 139(13):4879-4886. PMID: 28278372.
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    19. Hartwig J. Catalyst-Controlled Site-Selective Bond Activation. Acc Chem Res. 2017 Mar 21; 50(3):549-555. PMID: 28945414.
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    20. Jin Y, Chen M, Ge S, Hartwig J. Palladium-Catalyzed, Enantioselective a-Arylation of a-Fluorooxindoles. Org Lett. 2017 Mar 17; 19(6):1390-1393. PMID: 28263071.
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    21. Ge S, Green RA, Hartwig J. Correction to "Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex". J Am Chem Soc. 2017 03 01; 139(8):3300. PMID: 28212008.
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    22. Dydio P, Key HM, Hayashi H, Clark DS, Hartwig J. Chemoselective, Enzymatic C-H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor. J Am Chem Soc. 2017 02 08; 139(5):1750-1753. PMID: 28080030.
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    23. Jiang X, Beiger JJ, Hartwig J. Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis. J Am Chem Soc. 2017 01 11; 139(1):87-90. PMID: 27977923.
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    24. Jiao Z, Beiger JJ, Jin Y, Ge S, Zhou JS, Hartwig J. Palladium-Catalyzed Enantioselective a-Arylation of a-Fluoroketones. J Am Chem Soc. 2016 12 14; 138(49):15980-15986. PMID: 27960323.
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    25. Lee SY, Hartwig J. Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation. J Am Chem Soc. 2016 11 23; 138(46):15278-15284. PMID: 27797512.
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    26. Karimov RR, Sharma A, Hartwig J. Late Stage Azidation of Complex Molecules. ACS Cent Sci. 2016 Oct 26; 2(10):715-724. PMID: 27800554.
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    27. Morstein J, Kalkman ED, Cheng C, Hartwig J. Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles. Org Lett. 2016 Oct 21; 18(20):5244-5247. PMID: 27689746.
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    28. Peacock DM, Roos CB, Hartwig J. Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile. ACS Cent Sci. 2016 Sep 28; 2(9):647-652. PMID: 27725963.
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    29. Cheng C, Watts A, Hillmyer MA, Hartwig J. Polysilylether: A Degradable Polymer from Biorenewable Feedstocks. Angew Chem Int Ed Engl. 2016 Sep 19; 55(39):11872-6. PMID: 27572134.
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    30. Chen M, Hartwig J. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Angew Chem Int Ed Engl. 2016 Sep 12; 55(38):11651-5. PMID: 27531137.
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    31. Strom AE, Balcells D, Hartwig J. Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes. ACS Catal. 2016 Sep 02; 6:5651-5665. PMID: 28713642.
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    32. Zhang QW, Brusoe AT, Mascitti V, Hesp KD, Blakemore DC, Kohrt JT, Hartwig J. Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers. Angew Chem Int Ed Engl. 2016 Aug 08; 55(33):9758-62. PMID: 27384710.
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    33. Key HM, Dydio P, Clark DS, Hartwig J. Abiological catalysis by artificial haem proteins containing noble metals in place of iron. Nature. 2016 06 23; 534(7608):534-7. PMID: 27296224.
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    34. Lee T, Hartwig J. Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds. Angew Chem Int Ed Engl. 2016 Jul 18; 55(30):8723-7. PMID: 27253898; PMCID: PMC4976637 [Available on 07/18/17].
    35. Morstein J, Hou H, Cheng C, Hartwig J. Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ]. Angew Chem Int Ed Engl. 2016 Jul 04; 55(28):8054-7. PMID: 27214849; PMCID: PMC4976628 [Available on 07/04/17].
    36. Xi Y, Hartwig J. Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes through Catalytic Regioselective Hydroboration. J Am Chem Soc. 2016 06 01; 138(21):6703-6. PMID: 27167490.
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    37. Hartwig J, Larsen MA. Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities. ACS Cent Sci. 2016 May 25; 2(5):281-92. PMID: 27294201; PMCID: PMC4898263.
    38. Jiang X, Chen W, Hartwig J. Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic a-Alkoxy Ketones. Angew Chem Int Ed Engl. 2016 May 04; 55(19):5819-23. PMID: 27038004; PMCID: PMC4969080 [Available on 05/04/17].
    39. Arlow SI, Hartwig J. Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling. Angew Chem Int Ed Engl. 2016 Mar 24; 55(14):4567-72. PMID: 26929068; PMCID: PMC4956475 [Available on 03/24/17].
    40. Larsen MA, Cho SH, Hartwig J. Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C-H Bonds. J Am Chem Soc. 2016 Jan 27; 138(3):762-5. PMID: 26745739; PMCID: PMC4809204 [Available on 01/27/17].
    41. Wang DY, Choliy Y, Haibach MC, Hartwig J, Krogh-Jespersen K, Goldman AS. Assessment of the Electronic Factors Determining the Thermodynamics of "Oxidative Addition" of C-H and N-H Bonds to Ir(I) Complexes. J Am Chem Soc. 2016 Jan 13; 138(1):149-63. PMID: 26652221.
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    42. Hartwig J. Evolution of C-H Bond Functionalization from Methane to Methodology. J Am Chem Soc. 2016 Jan 13; 138(1):2-24. PMID: 26566092; PMCID: PMC4809212 [Available on 01/13/17].
    43. Gao F, Webb JD, Hartwig J. Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C-O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments. Angew Chem Int Ed Engl. 2016 Jan 22; 55(4):1474-8. PMID: 26666391.
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    44. Xi Y, Butcher TW, Zhang J, Hartwig J. Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes. Angew Chem Int Ed Engl. 2016 Jan 11; 55(2):776-80. PMID: 26592363.
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    45. Madrahimov ST, Li Q, Sharma A, Hartwig J. Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution. J Am Chem Soc. 2015 Dec 02; 137(47):14968-81. PMID: 26498382; PMCID: PMC4699445 [Available on 12/02/16].
    46. Chen M, Hartwig J. Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. J Am Chem Soc. 2015 Nov 04; 137(43):13972-9. PMID: 26441002.
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    47. Schramm Y, Takeuchi M, Semba K, Nakao Y, Hartwig J. Anti-Markovnikov hydroheteroarylation of unactivated alkenes with indoles, pyrroles, benzofurans, and furans catalyzed by a nickel-N-heterocyclic carbene system. J Am Chem Soc. 2015 Sep 30; 137(38):12215-8. PMID: 26334367.
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    48. Brusoe AT, Hartwig J. Palladium-Catalyzed Arylation of Fluoroalkylamines. J Am Chem Soc. 2015 Jul 08; 137(26):8460-8. PMID: 26065341; PMCID: PMC4699424.
    49. Larsen MA, Wilson CV, Hartwig J. Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity. J Am Chem Soc. 2015 Jul 08; 137(26):8633-43. PMID: 26076367.
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    50. Key HM, Clark DS, Hartwig J. Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand. J Am Chem Soc. 2015 Jul 01; 137(25):8261-8. PMID: 26020584.
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    51. Lee T, Wilson TW, Berg R, Ryberg P, Hartwig J. Rhodium-catalyzed enantioselective silylation of arene C-H bonds: desymmetrization of diarylmethanols. J Am Chem Soc. 2015 Jun 03; 137(21):6742-5. PMID: 25948056; PMCID: PMC4699421.
    52. Green RA, Hartwig J. Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts. Angew Chem Int Ed Engl. 2015 Mar 16; 54(12):3768-72. PMID: 25711163; PMCID: PMC4480680.
    53. Cheng C, Hartwig J. Catalytic Silylation of Unactivated C-H Bonds. Chem Rev. 2015 Sep 09; 115(17):8946-75. PMID: 25714857.
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    54. Sharma A, Hartwig J. Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization. Nature. 2015 Jan 29; 517(7536):600-4. PMID: 25631448; PMCID: PMC4311404.
    55. Cheng C, Hartwig J. Iridium-catalyzed silylation of aryl C-H bonds. J Am Chem Soc. 2015 Jan 21; 137(2):592-5. PMID: 25514197.
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    56. Tran BL, Driess M, Hartwig J. Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes. J Am Chem Soc. 2014 Dec 10; 136(49):17292-301. PMID: 25389772; PMCID: PMC4262675.
    57. Chen W, Chen M, Hartwig J. Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates. J Am Chem Soc. 2014 Nov 12; 136(45):15825-8. PMID: 25337972; PMCID: PMC4235373.
    58. Ge S, Arlow SI, Mormino MG, Hartwig J. Pd-catalyzed a-arylation of trimethylsilyl enolates of a,a-difluoroacetamides. J Am Chem Soc. 2014 Oct 15; 136(41):14401-4. PMID: 25254966; PMCID: PMC4210146.
    59. Chen M, Hartwig J. Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones. Angew Chem Int Ed Engl. 2014 Nov 03; 53(45):12172-6. PMID: 25223593; PMCID: PMC4214550.
    60. Bair JS, Schramm Y, Sergeev AG, Clot E, Eisenstein O, Hartwig J. Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes. J Am Chem Soc. 2014 Sep 24; 136(38):13098-101. PMID: 25171744.
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    61. Green RA, Hartwig J. Palladium-catalyzed amination of aryl chlorides and bromides with ammonium salts. Org Lett. 2014 Sep 05; 16(17):4388-91. PMID: 25133675; PMCID: PMC4260968.
    62. Cheng C, Hartwig J. Mechanism of the rhodium-catalyzed silylation of arene C-H bonds. J Am Chem Soc. 2014 Aug 27; 136(34):12064-72. PMID: 25082802.
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    63. Sevov CS, Hartwig J. Iridium-catalyzed oxidative olefination of furans with unactivated alkenes. J Am Chem Soc. 2014 Jul 30; 136(30):10625-31. PMID: 25032781.
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    64. Fier PS, Hartwig J. Synthesis and late-stage functionalization of complex molecules through C-H fluorination and nucleophilic aromatic substitution. J Am Chem Soc. 2014 Jul 16; 136(28):10139-47. PMID: 24918484; PMCID: PMC4227713.
    65. Li Q, Driess M, Hartwig J. Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. Angew Chem Int Ed Engl. 2014 Aug 04; 53(32):8471-4. PMID: 24962972.
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    66. Chen M, Hartwig J. Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from a,ß-unsaturated ketones. Angew Chem Int Ed Engl. 2014 Aug 11; 53(33):8691-5. PMID: 24917569; PMCID: PMC4159307.
    67. Li Q, Liskey CW, Hartwig J. Regioselective borylation of the C-H bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-H bonds beta to nitrogen and oxygen. J Am Chem Soc. 2014 Jun 18; 136(24):8755-65. PMID: 24836159.
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    68. Li B, Driess M, Hartwig J. Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. J Am Chem Soc. 2014 May 07; 136(18):6586-9. PMID: 24734777.
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    69. Mormino MG, Fier PS, Hartwig J. Copper-mediated perfluoroalkylation of heteroaryl bromides with (phen)CuRF. Org Lett. 2014 Mar 21; 16(6):1744-7. PMID: 24621138; PMCID: PMC3993863.
    70. Ge S, Chaladaj W, Hartwig J. Pd-catalyzed a-arylation of a,a-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes. J Am Chem Soc. 2014 Mar 19; 136(11):4149-52. PMID: 24588379; PMCID: PMC3985691.
    71. Larsen MA, Hartwig J. Iridium-catalyzed C-H borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism. J Am Chem Soc. 2014 Mar 19; 136(11):4287-99. PMID: 24506058.
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    72. Cheng C, Hartwig J. Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol. Science. 2014 Feb 21; 343(6173):853-7. PMID: 24558154.
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    73. Sevov CS, Zhou JS, Hartwig J. Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles. J Am Chem Soc. 2014 Feb 26; 136(8):3200-7. PMID: 24483848.
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    74. Tran BL, Li B, Driess M, Hartwig J. Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes. J Am Chem Soc. 2014 Feb 12; 136(6):2555-63. PMID: 24405209; PMCID: PMC3985719.
    75. Ge S, Green RA, Hartwig J. Controlling first-row catalysts: amination of aryl and heteroaryl chlorides and bromides with primary aliphatic amines catalyzed by a BINAP-ligated single-component Ni(0) complex. J Am Chem Soc. 2014 Jan 29; 136(4):1617-27. PMID: 24397570.
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    76. Denard CA, Huang H, Bartlett MJ, Lu L, Tan Y, Zhao H, Hartwig J. Cooperative tandem catalysis by an organometallic complex and a metalloenzyme. Angew Chem Int Ed Engl. 2014 Jan 07; 53(2):465-9. PMID: 24536102.
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    77. Chen W, Hartwig J. Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones. J Am Chem Soc. 2014 Jan 08; 136(1):377-82. PMID: 24295427; PMCID: PMC3989892.
    78. Fier PS, Hartwig J. Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction. Science. 2013 Nov 22; 342(6161):956-60. PMID: 24264986.
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    79. Sharma A, Hartwig J. Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification. J Am Chem Soc. 2013 Nov 27; 135(47):17983-9. PMID: 24156776; PMCID: PMC3911985.
    80. Gallego D, Brück A, Irran E, Meier F, Kaupp M, Driess M, Hartwig J. From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction. J Am Chem Soc. 2013 Oct 16; 135(41):15617-26. PMID: 24053603.
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    81. Strom AE, Hartwig J. One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination. J Org Chem. 2013 Sep 06; 78(17):8909-14. PMID: 23899320; PMCID: PMC3800136.
    82. Hama T, Ge S, Hartwig J. Palladium-catalyzed a-arylation of zinc enolates of esters: reaction conditions and substrate scope. J Org Chem. 2013 Sep 06; 78(17):8250-66. PMID: 23931445; PMCID: PMC3800138.
    83. Cheng C, Simmons EM, Hartwig J. Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8984-9. PMID: 23857914.
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    84. Sevov CS, Hartwig J. Iridium-catalyzed, intermolecular hydroetherification of unactivated aliphatic alkenes with phenols. J Am Chem Soc. 2013 Jun 26; 135(25):9303-6. PMID: 23758128.
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    85. Shrestha R, Mukherjee P, Tan Y, Litman ZC, Hartwig J. Sterically controlled, palladium-catalyzed intermolecular amination of arenes. J Am Chem Soc. 2013 Jun 12; 135(23):8480-3. PMID: 23678959.
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    86. Cho SH, Hartwig J. Iridium-catalyzed borylation of secondary benzylic C-H bonds directed by a hydrosilane. J Am Chem Soc. 2013 Jun 05; 135(22):8157-60. PMID: 23682736.
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    87. Liskey CW, Hartwig J. Iridium-catalyzed C-H borylation of cyclopropanes. J Am Chem Soc. 2013 Mar 06; 135(9):3375-8. PMID: 23421575.
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    88. Fier PS, Luo J, Hartwig J. Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex. J Am Chem Soc. 2013 Feb 20; 135(7):2552-9. PMID: 23384209; PMCID: PMC3619937.
    89. Sevov CS, Hartwig J. Iridium-catalyzed intermolecular asymmetric hydroheteroarylation of bicycloalkenes. J Am Chem Soc. 2013 Feb 13; 135(6):2116-9. PMID: 23346874.
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    90. Chen W, Hartwig J. Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion. J Am Chem Soc. 2013 Feb 13; 135(6):2068-71. PMID: 23286279; PMCID: PMC3595042.
    91. Fier PS, Hartwig J. Synthesis of difluoromethyl ethers with difluoromethyltriflate. Angew Chem Int Ed Engl. 2013 Feb 11; 52(7):2092-5. PMID: 23307535; PMCID: PMC3829639.
    92. Partridge BM, Hartwig J. Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation. Org Lett. 2013 Jan 04; 15(1):140-3. PMID: 23256483.
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    93. Sergeev AG, Webb JD, Hartwig J. A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation. J Am Chem Soc. 2012 Dec 19; 134(50):20226-9. PMID: 23163756.
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    94. Chen W, Hartwig J. Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. J Am Chem Soc. 2012 Sep 19; 134(37):15249-52. PMID: 22954355; PMCID: PMC3487469.
    95. Hanley PS, Marquard SL, Cundari TR, Hartwig J. Reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes. J Am Chem Soc. 2012 Sep 19; 134(37):15281-4. PMID: 22934822.
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    96. Liskey CW, Hartwig J. Iridium-catalyzed borylation of secondary C-H bonds in cyclic ethers. J Am Chem Soc. 2012 Aug 01; 134(30):12422-5. PMID: 22804581.
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    97. Sevov CS, Zhou J, Hartwig J. Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides. J Am Chem Soc. 2012 Jul 25; 134(29):11960-3. PMID: 22780090.
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    98. Fier PS, Hartwig J. Copper-mediated fluorination of aryl iodides. J Am Chem Soc. 2012 Jul 04; 134(26):10795-8. PMID: 22709145; PMCID: PMC3487470.
    99. Madrahimov ST, Hartwig J. Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes. J Am Chem Soc. 2012 May 16; 134(19):8136-47. PMID: 22486270; PMCID: PMC3368983.
    100. Fier PS, Hartwig J. Copper-mediated difluoromethylation of aryl and vinyl iodides. J Am Chem Soc. 2012 Mar 28; 134(12):5524-7. PMID: 22397683; PMCID: PMC3324264.
    101. Klinkenberg JL, Hartwig J. Reductive elimination from arylpalladium cyanide complexes. J Am Chem Soc. 2012 Apr 04; 134(13):5758-61. PMID: 22352451; PMCID: PMC3360980.
    102. Simmons EM, Hartwig J. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes. Angew Chem Int Ed Engl. 2012 Mar 26; 51(13):3066-72. PMID: 22392731.
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    103. Simmons EM, Hartwig J. Catalytic functionalization of unactivated primary C-H bonds directed by an alcohol. Nature. 2012 Feb 29; 483(7387):70-3. PMID: 22382981.
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    104. Tan Y, Barrios-Landeros F, Hartwig J. Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers. J Am Chem Soc. 2012 Feb 29; 134(8):3683-6. PMID: 22313324; PMCID: PMC3320665.
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    154. Vo GD, Hartwig J. Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. Angew Chem Int Ed Engl. 2008; 47(11):2127-30. PMID: 18260078.
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    169. Shekhar S, Trantow B, Leitner A, Hartwig J. Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products. J Am Chem Soc. 2006 Sep 13; 128(36):11770-1. PMID: 16953612.
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    175. Takemiya A, Hartwig J. Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. J Am Chem Soc. 2006 May 10; 128(18):6042-3. PMID: 16669666.
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    202. Krug C, Hartwig J. Imine insertion into a late metal-carbon bond to form a stable amido complex. J Am Chem Soc. 2004 Mar 10; 126(9):2694-5. PMID: 14995174.
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    210. Roy AH, Hartwig J. Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature. J Am Chem Soc. 2003 Jul 23; 125(29):8704-5. PMID: 12862447.
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    211. Stauffer SR, Hartwig J. Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study. J Am Chem Soc. 2003 Jun 11; 125(23):6977-85. PMID: 12783551.
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    212. Utsunomiya M, Kuwano R, Kawatsura M, Hartwig J. Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes. J Am Chem Soc. 2003 May 14; 125(19):5608-9. PMID: 12733880.
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    213. Hooper MW, Utsunomiya M, Hartwig J. Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. J Org Chem. 2003 Apr 04; 68(7):2861-73. PMID: 12662063.
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    214. Culkin DA, Hartwig J. Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. Acc Chem Res. 2003 Apr; 36(4):234-45. PMID: 12693921.
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    215. López F, Ohmura T, Hartwig J. Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides. J Am Chem Soc. 2003 Mar 26; 125(12):3426-7. PMID: 12643693.
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    216. Webster CE, Fan Y, Hall MB, Kunz D, Hartwig J. Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation. J Am Chem Soc. 2003 Jan 29; 125(4):858-9. PMID: 12537470.
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    217. Ohmura T, Hartwig J. Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. J Am Chem Soc. 2002 Dec 25; 124(51):15164-5. PMID: 12487578.
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    218. Stambuli JP, Kuwano R, Hartwig J. Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature. Angew Chem Int Ed Engl. 2002 Dec 16; 41(24):4746-8. PMID: 12481346.
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    219. Jørgensen M, Lee S, Liu X, Wolkowski JP, Hartwig J. Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates. J Am Chem Soc. 2002 Oct 23; 124(42):12557-65. PMID: 12381200.
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    220. Culkin DA, Hartwig J. Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles. J Am Chem Soc. 2002 Aug 14; 124(32):9330-1. PMID: 12167001.
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    221. Stambuli JP, Bühl M, Hartwig J. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J Am Chem Soc. 2002 Aug 14; 124(32):9346-7. PMID: 12167009.
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    222. Ranasinghe MI, Varnavski OP, Pawlas J, Hauck SI, Louie J, Hartwig J, Goodson T. Femtosecond excitation energy transport in triarylamine dendrimers. J Am Chem Soc. 2002 Jun 12; 124(23):6520-1. PMID: 12047157.
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    223. Schlummer B, Hartwig J. Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Org Lett. 2002 May 02; 4(9):1471-4. PMID: 11975606.
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    224. Pawlas J, Nakao Y, Kawatsura M, Hartwig J. A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism. J Am Chem Soc. 2002 Apr 10; 124(14):3669-79. PMID: 11929257.
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    225. Krug C, Hartwig J. Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. J Am Chem Soc. 2002 Feb 27; 124(8):1674-9. PMID: 11853443.
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    226. Nettekoven U, Hartwig J. A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. J Am Chem Soc. 2002 Feb 20; 124(7):1166-7. PMID: 11841274.
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    227. Kondo Y, García-Cuadrado D, Hartwig J, Boaen NK, Wagner NL, Hillmyer MA. Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. J Am Chem Soc. 2002 Feb 20; 124(7):1164-5. PMID: 11841273.
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    228. Ishiyama T, Takagi J, Ishida K, Miyaura N, Anastasi NR, Hartwig J. Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. J Am Chem Soc. 2002 Jan 23; 124(3):390-1. PMID: 11792205.
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