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    Hartwig, John

    TitleChemist Senior Faculty SE
    SchoolLawrence Berkeley National Lab
    DepartmentChemical Sciences
    Address1 Cyclotron Road
    Berkeley CA 94720
    Phone510/642-2038
    vCardDownload vCard

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      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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      1. Xi Y, Hartwig J. Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes. J Am Chem Soc. 2017 Sep 13; 139(36):12758-12772. PMID: 28787137.
        View in: PubMed
      2. Su B, Hartwig J. Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C-H Bonds. J Am Chem Soc. 2017 Sep 06; 139(35):12137-12140. PMID: 28820264.
        View in: PubMed
      3. Bunescu A, Lee S, Li Q, Hartwig J. Catalytic Hydroxylation of Polyethylenes. ACS Cent Sci. 2017 Aug 23; 3(8):895-903. PMID: 28852704.
        View in: PubMed
      4. Troshin K, Hartwig J. Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions. Science. 2017 Jul 14; 357(6347):175-181. PMID: 28706066.
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      5. Jiang X, Hartwig J. Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates. Angew Chem Int Ed Engl. 2017 Jul 17; 56(30):8887-8891. PMID: 28597600.
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      6. Key HM, Dydio P, Liu Z, Rha JY, Nazarenko A, Seyedkazemi V, Clark DS, Hartwig J. Beyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes. ACS Cent Sci. 2017 Apr 26; 3(4):302-308. PMID: 28470047.
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      7. Lee T, Hartwig J. Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds. J Am Chem Soc. 2017 Apr 05; 139(13):4879-4886. PMID: 28278372.
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      8. Jin Y, Chen M, Ge S, Hartwig J. Palladium-Catalyzed, Enantioselective a-Arylation of a-Fluorooxindoles. Org Lett. 2017 Mar 17; 19(6):1390-1393. PMID: 28263071.
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      9. Ge S, Green RA, Hartwig J. Correction to "Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex". J Am Chem Soc. 2017 Mar 01; 139(8):3300. PMID: 28212008.
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      10. Dydio P, Key HM, Hayashi H, Clark DS, Hartwig J. Chemoselective, Enzymatic C-H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor. J Am Chem Soc. 2017 Feb 08; 139(5):1750-1753. PMID: 28080030.
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      11. Jiang X, Beiger JJ, Hartwig J. Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis. J Am Chem Soc. 2017 01 11; 139(1):87-90. PMID: 27977923.
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      12. Jiao Z, Beiger JJ, Jin Y, Ge S, Zhou JS, Hartwig J. Palladium-Catalyzed Enantioselective a-Arylation of a-Fluoroketones. J Am Chem Soc. 2016 Dec 14; 138(49):15980-15986. PMID: 27960323.
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      13. Lee SY, Hartwig J. Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation. J Am Chem Soc. 2016 Nov 23; 138(46):15278-15284. PMID: 27797512.
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      14. Dydio P, Key HM, Nazarenko A, Rha JY, Seyedkazemi V, Clark DS, Hartwig J. An artificial metalloenzyme with the kinetics of native enzymes. Science. 2016 10 07; 354(6308):102-106. PMID: 27846500.
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      15. Karimov RR, Sharma A, Hartwig J. Late Stage Azidation of Complex Molecules. ACS Cent Sci. 2016 Oct 26; 2(10):715-724. PMID: 27800554.
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      16. Morstein J, Kalkman ED, Cheng C, Hartwig J. Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles. Org Lett. 2016 Oct 21; 18(20):5244-5247. PMID: 27689746.
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      17. Peacock DM, Roos CB, Hartwig J. Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile. ACS Cent Sci. 2016 Sep 28; 2(9):647-652. PMID: 27725963.
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      18. Cheng C, Watts A, Hillmyer MA, Hartwig J. Polysilylether: A Degradable Polymer from Biorenewable Feedstocks. Angew Chem Int Ed Engl. 2016 Sep 19; 55(39):11872-6. PMID: 27572134.
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      19. Chen M, Hartwig J. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Angew Chem Int Ed Engl. 2016 Sep 12; 55(38):11651-5. PMID: 27531137.
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      20. Strom AE, Balcells D, Hartwig J. Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes. ACS Catal. 2016 Sep 02; 6:5651-5665. PMID: 28713642.
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      21. Zhang QW, Brusoe AT, Mascitti V, Hesp KD, Blakemore DC, Kohrt JT, Hartwig J. Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers. Angew Chem Int Ed Engl. 2016 Aug 08; 55(33):9758-62. PMID: 27384710.
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      22. Key HM, Dydio P, Clark DS, Hartwig J. Abiological catalysis by artificial haem proteins containing noble metals in place of iron. Nature. 2016 06 23; 534(7608):534-7. PMID: 27296224.
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      23. Lee T, Hartwig J. Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds. Angew Chem Int Ed Engl. 2016 Jul 18; 55(30):8723-7. PMID: 27253898; PMCID: PMC4976637 [Available on 07/18/17].
      24. Morstein J, Hou H, Cheng C, Hartwig J. Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ]. Angew Chem Int Ed Engl. 2016 Jul 04; 55(28):8054-7. PMID: 27214849; PMCID: PMC4976628 [Available on 07/04/17].
      25. Xi Y, Hartwig J. Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes through Catalytic Regioselective Hydroboration. J Am Chem Soc. 2016 Jun 01; 138(21):6703-6. PMID: 27167490.
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      26. Hartwig J, Larsen MA. Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities. ACS Cent Sci. 2016 May 25; 2(5):281-92. PMID: 27294201; PMCID: PMC4898263.
      27. Jiang X, Chen W, Hartwig J. Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic a-Alkoxy Ketones. Angew Chem Int Ed Engl. 2016 May 04; 55(19):5819-23. PMID: 27038004; PMCID: PMC4969080 [Available on 05/04/17].
      28. Arlow SI, Hartwig J. Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling. Angew Chem Int Ed Engl. 2016 Mar 24; 55(14):4567-72. PMID: 26929068; PMCID: PMC4956475 [Available on 03/24/17].
      29. Larsen MA, Cho SH, Hartwig J. Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C-H Bonds. J Am Chem Soc. 2016 Jan 27; 138(3):762-5. PMID: 26745739; PMCID: PMC4809204 [Available on 01/27/17].
      30. Wang DY, Choliy Y, Haibach MC, Hartwig J, Krogh-Jespersen K, Goldman AS. Assessment of the Electronic Factors Determining the Thermodynamics of "Oxidative Addition" of C-H and N-H Bonds to Ir(I) Complexes. J Am Chem Soc. 2016 Jan 13; 138(1):149-63. PMID: 26652221.
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      31. Hartwig J. Evolution of C-H Bond Functionalization from Methane to Methodology. J Am Chem Soc. 2016 Jan 13; 138(1):2-24. PMID: 26566092; PMCID: PMC4809212 [Available on 01/13/17].
      32. Gao F, Webb JD, Hartwig J. Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C-O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments. Angew Chem Int Ed Engl. 2016 Jan 22; 55(4):1474-8. PMID: 26666391.
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      33. Xi Y, Butcher TW, Zhang J, Hartwig J. Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes. Angew Chem Int Ed Engl. 2016 Jan 11; 55(2):776-80. PMID: 26592363.
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      34. Madrahimov ST, Li Q, Sharma A, Hartwig J. Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution. J Am Chem Soc. 2015 Dec 02; 137(47):14968-81. PMID: 26498382; PMCID: PMC4699445 [Available on 12/02/16].
      35. Chen M, Hartwig J. Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. J Am Chem Soc. 2015 Nov 04; 137(43):13972-9. PMID: 26441002.
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      36. Schramm Y, Takeuchi M, Semba K, Nakao Y, Hartwig J. Anti-Markovnikov hydroheteroarylation of unactivated alkenes with indoles, pyrroles, benzofurans, and furans catalyzed by a nickel-N-heterocyclic carbene system. J Am Chem Soc. 2015 Sep 30; 137(38):12215-8. PMID: 26334367.
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      37. Brusoe AT, Hartwig J. Palladium-Catalyzed Arylation of Fluoroalkylamines. J Am Chem Soc. 2015 Jul 08; 137(26):8460-8. PMID: 26065341; PMCID: PMC4699424.
      38. Larsen MA, Wilson CV, Hartwig J. Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity. J Am Chem Soc. 2015 Jul 08; 137(26):8633-43. PMID: 26076367.
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      39. Key HM, Clark DS, Hartwig J. Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand. J Am Chem Soc. 2015 Jul 01; 137(25):8261-8. PMID: 26020584.
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      40. Lee T, Wilson TW, Berg R, Ryberg P, Hartwig J. Rhodium-catalyzed enantioselective silylation of arene C-H bonds: desymmetrization of diarylmethanols. J Am Chem Soc. 2015 Jun 03; 137(21):6742-5. PMID: 25948056; PMCID: PMC4699421.
      41. Cheng C, Hartwig J. Catalytic Silylation of Unactivated C-H Bonds. Chem Rev. 2015 Sep 09; 115(17):8946-75. PMID: 25714857.
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      42. Green RA, Hartwig J. Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts. Angew Chem Int Ed Engl. 2015 Mar 16; 54(12):3768-72. PMID: 25711163; PMCID: PMC4480680.
      43. Sharma A, Hartwig J. Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization. Nature. 2015 Jan 29; 517(7536):600-4. PMID: 25631448; PMCID: PMC4311404.
      44. Cheng C, Hartwig J. Iridium-catalyzed silylation of aryl C-H bonds. J Am Chem Soc. 2015 Jan 21; 137(2):592-5. PMID: 25514197.
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      45. Tran BL, Driess M, Hartwig J. Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes. J Am Chem Soc. 2014 Dec 10; 136(49):17292-301. PMID: 25389772; PMCID: PMC4262675.
      46. Chen W, Chen M, Hartwig J. Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates. J Am Chem Soc. 2014 Nov 12; 136(45):15825-8. PMID: 25337972; PMCID: PMC4235373.
      47. Ge S, Arlow SI, Mormino MG, Hartwig J. Pd-catalyzed a-arylation of trimethylsilyl enolates of a,a-difluoroacetamides. J Am Chem Soc. 2014 Oct 15; 136(41):14401-4. PMID: 25254966; PMCID: PMC4210146.
      48. Chen M, Hartwig J. Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones. Angew Chem Int Ed Engl. 2014 Nov 03; 53(45):12172-6. PMID: 25223593; PMCID: PMC4214550.
      49. Bair JS, Schramm Y, Sergeev AG, Clot E, Eisenstein O, Hartwig J. Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes. J Am Chem Soc. 2014 Sep 24; 136(38):13098-101. PMID: 25171744.
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      50. Green RA, Hartwig J. Palladium-catalyzed amination of aryl chlorides and bromides with ammonium salts. Org Lett. 2014 Sep 05; 16(17):4388-91. PMID: 25133675; PMCID: PMC4260968.
      51. Cheng C, Hartwig J. Mechanism of the rhodium-catalyzed silylation of arene C-H bonds. J Am Chem Soc. 2014 Aug 27; 136(34):12064-72. PMID: 25082802.
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      52. Sevov CS, Hartwig J. Iridium-catalyzed oxidative olefination of furans with unactivated alkenes. J Am Chem Soc. 2014 Jul 30; 136(30):10625-31. PMID: 25032781.
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      53. Fier PS, Hartwig J. Synthesis and late-stage functionalization of complex molecules through C-H fluorination and nucleophilic aromatic substitution. J Am Chem Soc. 2014 Jul 16; 136(28):10139-47. PMID: 24918484; PMCID: PMC4227713.
      54. Li Q, Driess M, Hartwig J. Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. Angew Chem Int Ed Engl. 2014 Aug 04; 53(32):8471-4. PMID: 24962972.
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      55. Chen M, Hartwig J. Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from a,ß-unsaturated ketones. Angew Chem Int Ed Engl. 2014 Aug 11; 53(33):8691-5. PMID: 24917569; PMCID: PMC4159307.
      56. Li Q, Liskey CW, Hartwig J. Regioselective borylation of the C-H bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-H bonds beta to nitrogen and oxygen. J Am Chem Soc. 2014 Jun 18; 136(24):8755-65. PMID: 24836159.
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      57. Li B, Driess M, Hartwig J. Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. J Am Chem Soc. 2014 May 07; 136(18):6586-9. PMID: 24734777.
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      58. Mormino MG, Fier PS, Hartwig J. Copper-mediated perfluoroalkylation of heteroaryl bromides with (phen)CuRF. Org Lett. 2014 Mar 21; 16(6):1744-7. PMID: 24621138; PMCID: PMC3993863.
      59. Ge S, Chaladaj W, Hartwig J. Pd-catalyzed a-arylation of a,a-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes. J Am Chem Soc. 2014 Mar 19; 136(11):4149-52. PMID: 24588379; PMCID: PMC3985691.
      60. Larsen MA, Hartwig J. Iridium-catalyzed C-H borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism. J Am Chem Soc. 2014 Mar 19; 136(11):4287-99. PMID: 24506058.
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      61. Cheng C, Hartwig J. Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol. Science. 2014 Feb 21; 343(6173):853-7. PMID: 24558154.
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      62. Sevov CS, Zhou JS, Hartwig J. Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles. J Am Chem Soc. 2014 Feb 26; 136(8):3200-7. PMID: 24483848.
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      63. Tran BL, Li B, Driess M, Hartwig J. Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes. J Am Chem Soc. 2014 Feb 12; 136(6):2555-63. PMID: 24405209; PMCID: PMC3985719.
      64. Ge S, Green RA, Hartwig J. Controlling first-row catalysts: amination of aryl and heteroaryl chlorides and bromides with primary aliphatic amines catalyzed by a BINAP-ligated single-component Ni(0) complex. J Am Chem Soc. 2014 Jan 29; 136(4):1617-27. PMID: 24397570; PMCID: PMC3985683.
      65. Denard CA, Huang H, Bartlett MJ, Lu L, Tan Y, Zhao H, Hartwig J. Cooperative tandem catalysis by an organometallic complex and a metalloenzyme. Angew Chem Int Ed Engl. 2014 Jan 07; 53(2):465-9. PMID: 24536102.
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      66. Chen W, Hartwig J. Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones. J Am Chem Soc. 2014 Jan 08; 136(1):377-82. PMID: 24295427; PMCID: PMC3989892.
      67. Fier PS, Hartwig J. Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction. Science. 2013 Nov 22; 342(6161):956-60. PMID: 24264986.
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      68. Sharma A, Hartwig J. Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification. J Am Chem Soc. 2013 Nov 27; 135(47):17983-9. PMID: 24156776; PMCID: PMC3911985.
      69. Gallego D, Brück A, Irran E, Meier F, Kaupp M, Driess M, Hartwig J. From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction. J Am Chem Soc. 2013 Oct 16; 135(41):15617-26. PMID: 24053603.
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      70. Strom AE, Hartwig J. One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination. J Org Chem. 2013 Sep 06; 78(17):8909-14. PMID: 23899320; PMCID: PMC3800136.
      71. Hama T, Ge S, Hartwig J. Palladium-catalyzed a-arylation of zinc enolates of esters: reaction conditions and substrate scope. J Org Chem. 2013 Sep 06; 78(17):8250-66. PMID: 23931445; PMCID: PMC3800138.
      72. Cheng C, Simmons EM, Hartwig J. Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8984-9. PMID: 23857914.
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      73. Sevov CS, Hartwig J. Iridium-catalyzed, intermolecular hydroetherification of unactivated aliphatic alkenes with phenols. J Am Chem Soc. 2013 Jun 26; 135(25):9303-6. PMID: 23758128.
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      74. Shrestha R, Mukherjee P, Tan Y, Litman ZC, Hartwig J. Sterically controlled, palladium-catalyzed intermolecular amination of arenes. J Am Chem Soc. 2013 Jun 12; 135(23):8480-3. PMID: 23678959.
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      75. Cho SH, Hartwig J. Iridium-catalyzed borylation of secondary benzylic C-H bonds directed by a hydrosilane. J Am Chem Soc. 2013 Jun 05; 135(22):8157-60. PMID: 23682736.
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      76. Liskey CW, Hartwig J. Iridium-catalyzed C-H borylation of cyclopropanes. J Am Chem Soc. 2013 Mar 06; 135(9):3375-8. PMID: 23421575.
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      77. Fier PS, Luo J, Hartwig J. Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex. J Am Chem Soc. 2013 Feb 20; 135(7):2552-9. PMID: 23384209; PMCID: PMC3619937.
      78. Sevov CS, Hartwig J. Iridium-catalyzed intermolecular asymmetric hydroheteroarylation of bicycloalkenes. J Am Chem Soc. 2013 Feb 13; 135(6):2116-9. PMID: 23346874.
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      79. Chen W, Hartwig J. Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion. J Am Chem Soc. 2013 Feb 13; 135(6):2068-71. PMID: 23286279; PMCID: PMC3595042.
      80. Fier PS, Hartwig J. Synthesis of difluoromethyl ethers with difluoromethyltriflate. Angew Chem Int Ed Engl. 2013 Feb 11; 52(7):2092-5. PMID: 23307535; PMCID: PMC3829639.
      81. Partridge BM, Hartwig J. Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation. Org Lett. 2013 Jan 04; 15(1):140-3. PMID: 23256483.
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      82. Sergeev AG, Webb JD, Hartwig J. A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation. J Am Chem Soc. 2012 Dec 19; 134(50):20226-9. PMID: 23163756.
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      83. Chen W, Hartwig J. Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. J Am Chem Soc. 2012 Sep 19; 134(37):15249-52. PMID: 22954355; PMCID: PMC3487469.
      84. Hanley PS, Marquard SL, Cundari TR, Hartwig J. Reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes. J Am Chem Soc. 2012 Sep 19; 134(37):15281-4. PMID: 22934822.
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      85. Liskey CW, Hartwig J. Iridium-catalyzed borylation of secondary C-H bonds in cyclic ethers. J Am Chem Soc. 2012 Aug 01; 134(30):12422-5. PMID: 22804581.
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      86. Sevov CS, Zhou J, Hartwig J. Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides. J Am Chem Soc. 2012 Jul 25; 134(29):11960-3. PMID: 22780090.
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      87. Fier PS, Hartwig J. Copper-mediated fluorination of aryl iodides. J Am Chem Soc. 2012 Jul 04; 134(26):10795-8. PMID: 22709145; PMCID: PMC3487470.
      88. Madrahimov ST, Hartwig J. Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes. J Am Chem Soc. 2012 May 16; 134(19):8136-47. PMID: 22486270; PMCID: PMC3368983.
      89. Fier PS, Hartwig J. Copper-mediated difluoromethylation of aryl and vinyl iodides. J Am Chem Soc. 2012 Mar 28; 134(12):5524-7. PMID: 22397683; PMCID: PMC3324264.
      90. Klinkenberg JL, Hartwig J. Reductive elimination from arylpalladium cyanide complexes. J Am Chem Soc. 2012 Apr 04; 134(13):5758-61. PMID: 22352451; PMCID: PMC3360980.
      91. Simmons EM, Hartwig J. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes. Angew Chem Int Ed Engl. 2012 Mar 26; 51(13):3066-72. PMID: 22392731.
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      92. Simmons EM, Hartwig J. Catalytic functionalization of unactivated primary C-H bonds directed by an alcohol. Nature. 2012 Feb 29; 483(7387):70-3. PMID: 22382981.
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      93. Tan Y, Barrios-Landeros F, Hartwig J. Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers. J Am Chem Soc. 2012 Feb 29; 134(8):3683-6. PMID: 22313324; PMCID: PMC3320665.
      94. Litvinas ND, Fier PS, Hartwig J. A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]. Angew Chem Int Ed Engl. 2012 Jan 09; 51(2):536-9. PMID: 22083965; PMCID: PMC3324659.
      95. Hartwig J. Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations. Acc Chem Res. 2012 Jun 19; 45(6):864-73. PMID: 22075137.
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      96. Ge S, Hartwig J. Nickel-catalyzed asymmetric a-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions. J Am Chem Soc. 2011 Oct 19; 133(41):16330-3. PMID: 21916501; PMCID: PMC3214653.
      97. Robbins DW, Hartwig J. A simple, multidimensional approach to high-throughput discovery of catalytic reactions. Science. 2011 Sep 09; 333(6048):1423-7. PMID: 21903809; PMCID: PMC3261636.
      98. Hanley PS, Hartwig J. Intermolecular migratory insertion of unactivated olefins into palladium-nitrogen bonds. Steric and electronic effects on the rate of migratory insertion. J Am Chem Soc. 2011 Oct 05; 133(39):15661-73. PMID: 21815675.
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      99. Sergeev AG, Hartwig J. Selective, nickel-catalyzed hydrogenolysis of aryl ethers. Science. 2011 Apr 22; 332(6028):439-43. PMID: 21512027.
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      100. Tan Y, Hartwig J. Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species. J Am Chem Soc. 2011 Mar 16; 133(10):3308-11. PMID: 21314146; PMCID: PMC3053425.
      101. Liu Z, Yamamichi H, Madrahimov ST, Hartwig J. Rhodium phosphine-p-arene intermediates in the hydroamination of alkenes. J Am Chem Soc. 2011 Mar 02; 133(8):2772-82. PMID: 21309512; PMCID: PMC3075068.
      102. Carrow BP, Hartwig J. Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions. J Am Chem Soc. 2011 Feb 23; 133(7):2116-9. PMID: 21280669; PMCID: PMC3041853.
      103. Liao X, Stanley LM, Hartwig J. Enantioselective total syntheses of (-)-taiwaniaquinone H and (-)-taiwaniaquinol B by iridium-catalyzed borylation and palladium-catalyzed asymmetric a-arylation. J Am Chem Soc. 2011 Feb 23; 133(7):2088-91. PMID: 21268578; PMCID: PMC3042318.
      104. Klinkenberg JL, Hartwig J. Catalytic organometallic reactions of ammonia. Angew Chem Int Ed Engl. 2011 Jan 03; 50(1):86-95. PMID: 20857466; PMCID: PMC3261073.
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      208. Culkin DA, Hartwig J. Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles. J Am Chem Soc. 2002 Aug 14; 124(32):9330-1. PMID: 12167001.
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      209. Stambuli JP, Bühl M, Hartwig J. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J Am Chem Soc. 2002 Aug 14; 124(32):9346-7. PMID: 12167009.
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      210. Ranasinghe MI, Varnavski OP, Pawlas J, Hauck SI, Louie J, Hartwig J, Goodson T. Femtosecond excitation energy transport in triarylamine dendrimers. J Am Chem Soc. 2002 Jun 12; 124(23):6520-1. PMID: 12047157.
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      211. Schlummer B, Hartwig J. Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Org Lett. 2002 May 02; 4(9):1471-4. PMID: 11975606.
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      212. Pawlas J, Nakao Y, Kawatsura M, Hartwig J. A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism. J Am Chem Soc. 2002 Apr 10; 124(14):3669-79. PMID: 11929257.
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      213. Krug C, Hartwig J. Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. J Am Chem Soc. 2002 Feb 27; 124(8):1674-9. PMID: 11853443.
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      214. Kondo Y, García-Cuadrado D, Hartwig J, Boaen NK, Wagner NL, Hillmyer MA. Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. J Am Chem Soc. 2002 Feb 20; 124(7):1164-5. PMID: 11841273.
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      215. Nettekoven U, Hartwig J. A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. J Am Chem Soc. 2002 Feb 20; 124(7):1166-7. PMID: 11841274.
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      216. Ishiyama T, Takagi J, Ishida K, Miyaura N, Anastasi NR, Hartwig J. Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. J Am Chem Soc. 2002 Jan 23; 124(3):390-1. PMID: 11792205.
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      217. Alcazar-Roman LM, Hartwig J. Mechanism of aryl chloride amination: base-induced oxidative addition. J Am Chem Soc. 2001 Dec 26; 123(51):12905-6. PMID: 11749551.
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      218. Chae HK, Eddaoudi M, Kim J, Hauck SI, Hartwig J, O'Keeffe M, Yaghi OM. Tertiary building units: synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1). J Am Chem Soc. 2001 Nov 21; 123(46):11482-3. PMID: 11707128.
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      219. Kawamura K, Hartwig J. Isolated Ir(V) boryl complexes and their reactions with hydrocarbons. J Am Chem Soc. 2001 Aug 29; 123(34):8422-3. PMID: 11516302.
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      220. Lee S, Beare NA, Hartwig J. Palladium-catalyzed alpha-arylation of esters and protected amino acids. J Am Chem Soc. 2001 Aug 29; 123(34):8410-1. PMID: 11516296.
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      221. Zhao J, Hesslink H, Hartwig J. Mechanism of beta-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. J Am Chem Soc. 2001 Aug 01; 123(30):7220-7. PMID: 11472149.
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      222. Culkin DA, Hartwig J. C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. J Am Chem Soc. 2001 Jun 20; 123(24):5816-7. PMID: 11403622.
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      223. Lee S, Hartwig J. Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations. J Org Chem. 2001 May 18; 66(10):3402-15. PMID: 11348123.
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      224. Stauffer SR, Beare NA, Stambuli JP, Hartwig J. Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery. J Am Chem Soc. 2001 May 16; 123(19):4641-2. PMID: 11457267.
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      225. Löber O, Kawatsura M, Hartwig J. Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions. J Am Chem Soc. 2001 May 09; 123(18):4366-7. PMID: 11457216.
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      226. Stambuli JP, Stauffer SR, Shaughnessy KH, Hartwig J. Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions. J Am Chem Soc. 2001 Mar 21; 123(11):2677-8. PMID: 11456943.
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      227. Roy AH, Hartwig J. Reductive elimination of aryl halides from palladium(II). J Am Chem Soc. 2001 Feb 14; 123(6):1232-3. PMID: 11456679.
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      228. Stauffer SR, Lee S, Stambuli JP, Hauck SI, Hartwig J. High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands. Org Lett. 2000 May 18; 2(10):1423-6. PMID: 10814463.
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