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    Arnold, John

    TitleChemist Faculty
    SchoolLawrence Berkeley National Lab
    DepartmentChemical Sciences
    Address1 Cyclotron Road
    Berkeley CA 94720
    Phone510/486-6843
    vCardDownload vCard

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      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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      1. Boreen MA, Parker BF, Hohloch S, Skeel BA, Arnold J. f-Block complexes of a m-terphenyl dithiocarboxylate ligand. Dalton Trans. 2018 Jan 07; 47(1):96-104. PMID: 29177271.
        View in: PubMed
      2. Ivanov AS, Leggett CJ, Parker BF, Zhang Z, Arnold J, Dai S, Abney CW, Bryantsev VS, Rao L. Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater. Nat Commun. 2017 Nov 16; 8(1):1560. PMID: 29146970.
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      3. Hohloch S, Garner ME, Parker BF, Arnold J. New supporting ligands in actinide chemistry: tetramethyltetraazaannulene complexes with thorium and uranium. Dalton Trans. 2017 Oct 17; 46(40):13768-13782. PMID: 28959804.
        View in: PubMed
      4. Lohrey TD, Bergman RG, Arnold J. Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand. Angew Chem Int Ed Engl. 2017 Nov 06; 56(45):14241-14245. PMID: 28929597.
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      5. Hohloch S, Pankhurst JR, Jaekel EE, Parker BF, Lussier DJ, Garner ME, Booth CH, Love JB, Arnold J. Benzoquinonoid-bridged dinuclear actinide complexes. Dalton Trans. 2017 Sep 12; 46(35):11615-11625. PMID: 28831470.
        View in: PubMed
      6. Garner ME, Parker BF, Hohloch S, Bergman RG, Arnold J. Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination. J Am Chem Soc. 2017 Sep 20; 139(37):12935-12938. PMID: 28892619.
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      7. Parker BF, Zhang Z, Leggett CJ, Arnold J, Rao L. Kinetics of complexation of V(v), U(vi), and Fe(iii) with glutaroimide-dioxime: studies by stopped-flow and conventional absorption spectroscopy. Dalton Trans. 2017 Aug 22; 46(33):11084-11096. PMID: 28787059.
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      8. Altman AB, Pemmaraju CD, Alayoglu S, Arnold J, Booth CH, Braun A, Bunker CE, Herve A, Minasian SG, Prendergast D, Shuh DK, Tyliszczak T. Chemical and Morphological Inhomogeneity of Aluminum Metal and Oxides from Soft X-ray Spectromicroscopy. Inorg Chem. 2017 May 15; 56(10):5710-5719. PMID: 28471186.
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      9. Settineri NS, Garner ME, Arnold J. A Thorium Chalcogenolate Series Generated by Atom Insertion into Thorium-Carbon Bonds. J Am Chem Soc. 2017 Apr 21. PMID: 28430420.
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      10. Kriegel BM, Naested LC, Nocton G, Lakshmi KV, Lohrey TD, Bergman RG, Arnold J. Redox-Initiated Reactivity of Dinuclear ß-Diketiminatoniobium Imido Complexes. Inorg Chem. 2017 Feb 06; 56(3):1626-1637. PMID: 28098983.
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      11. Ziegler JA, Buckley HL, Arnold J. Synthesis and reactivity of tantalum corrole complexes. Dalton Trans. 2017 Jan 17; 46(3):780-785. PMID: 27996068.
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      12. Boreen MA, Parker BF, Lohrey TD, Arnold J. A Homoleptic Uranium(III) Tris(aryl) Complex. J Am Chem Soc. 2016 Dec 14; 138(49):15865-15868. PMID: 27960342.
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      13. Armstrong KC, Hohloch S, Lohrey TD, Zarkesh RA, Arnold J, Anstey MR. Control of clustering behavior in anionic cerium(iii) corrole complexes: from oligomers to monomers. Dalton Trans. 2016 Nov 22; 45(46):18653-18660. PMID: 27827498.
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      14. Lohrey TD, Bergman RG, Arnold J. Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium ß-Diketiminate Complex. Inorg Chem. 2016 Nov 21; 55(22):11993-12000. PMID: 27934320.
        View in: PubMed
      15. Hohloch S, Kriegel BM, Bergman RG, Arnold J. Group 5 chemistry supported by ß-diketiminate ligands. Dalton Trans. 2016 Oct 12; 45(40):15725-15745. PMID: 27327510.
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      16. Garner ME, Hohloch S, Maron L, Arnold J. Carbon-Nitrogen Bond Cleavage by a Thorium-NHC-bpy Complex. Angew Chem Int Ed Engl. 2016 Oct 24; 55(44):13789-13792. PMID: 27699947.
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      17. Ziegler JA, Bergman RG, Arnold J. Unusual ?1 coordination of a ß-diketiminate ligand in niobium complexes. Dalton Trans. 2016 Aug 09; 45(32):12661-8. PMID: 27461382.
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      18. Abubekerov M, Eymann LY, Gianetti TL, Arnold J. Activation of heteroallenes by coordinatively unsaturated nickel(ii) alkyl complexes supported by the hydrotris(3-phenyl-5-methyl)pyrazolyl borate (Tp(Ph,Me)) ligand. Dalton Trans. 2016 Oct 07; 45(37):14581-90. PMID: 27334096.
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      19. Kriegel BM, Bergman RG, Arnold J. Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes. J Am Chem Soc. 2016 Jan 13; 138(1):52-5. PMID: 26698833.
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      20. Altman AB, Pemmaraju CD, Camp C, Arnold J, Minasian SG, Prendergast D, Shuh DK, Tyliszczak T. Theory and X-ray Absorption Spectroscopy for Aluminum Coordination Complexes – Al K-Edge Studies of Charge and Bonding in (BDI)Al, (BDI)AlR2, and (BDI)AlX2 Complexes. J Am Chem Soc. 2015 Aug 19; 137(32):10304-16. PMID: 26258886.
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      21. Nechayev M, Gianetti TL, Bergman RG, Arnold J. C-F sp(2) bond functionalization mediated by niobium complexes. Dalton Trans. 2015 Dec 07; 44(45):19494-500. PMID: 26216334.
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      22. Camp C, Maron L, Bergman RG, Arnold J. Activation of white phosphorus by low-valent group 5 complexes: formation and reactivity of cyclo-P4 inverted sandwich compounds. J Am Chem Soc. 2014 Dec 17; 136(50):17652-61. PMID: 25469924; PMCID: PMC4277768.
      23. Buckley HL, Rubin LK, Chrominski M, McNicholas BJ, Tsen KH, Gryko DT, Arnold J. Corroles that "click": modular synthesis of azido- and propargyl-functionalized metallocorrole complexes and convergent synthesis of a bis-corrole scaffold. Inorg Chem. 2014 Aug 04; 53(15):7941-50. PMID: 25029670.
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      24. Kriegel BM, Bergman RG, Arnold J. Generation of low-valent tantalum species by reversible C-H activation in a cyclometallated tantalum hydride complex. Dalton Trans. 2014 Jul 14; 43(26):10046-56. PMID: 24870398.
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      25. Ward AL, Lukens WW, Lu CC, Arnold J. Photochemical route to actinide-transition metal bonds: synthesis, characterization and reactivity of a series of thorium and uranium heterobimetallic complexes. J Am Chem Soc. 2014 Mar 05; 136(9):3647-54. PMID: 24498862.
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      26. Obenhuber AH, Gianetti TL, Berrebi X, Bergman RG, Arnold J. Reaction of (bisimido)niobium(V) complexes with organic azides: [3 + 2] cycloaddition and reversible cleavage of ß-diketiminato ligands involving nitrene transfer. J Am Chem Soc. 2014 Feb 26; 136(8):2994-7. PMID: 24524190.
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      27. Rozenel SS, Padilla R, Arnold J. Chemistry of reduced monomeric and dimeric cobalt complexes supported by a PNP pincer ligand. Inorg Chem. 2013 Oct 07; 52(19):11544-50. PMID: 24050728.
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      28. La Pierre HS, Minasian SG, Abubekerov M, Kozimor SA, Shuh DK, Tyliszczak T, Arnold J, Bergman RG, Toste FD. Vanadium bisimide bonding investigated by X-ray crystallography, 51V and 13C nuclear magnetic resonance spectroscopy, and V L(3,2)-edge X-ray absorption near-edge structure spectroscopy. Inorg Chem. 2013 Oct 07; 52(19):11650-60. PMID: 24024833.
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      29. Ward AL, Buckley HL, Lukens WW, Arnold J. Synthesis and characterization of thorium(IV) and uranium(IV) corrole complexes. J Am Chem Soc. 2013 Sep 18; 135(37):13965-71. PMID: 24004416.
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      30. Abubekerov M, Gianetti TL, Kunishita A, Arnold J. Synthesis and characterization of coordinatively unsaturated nickel(II) and manganese(II) alkyl complexes supported by the hydrotris(3-phenyl-5-methylpyrazolyl)borate (Tp(Ph,Me)) ligand. Dalton Trans. 2013 Aug 07; 42(29):10525-32. PMID: 23748480.
        View in: PubMed
      31. Gianetti TL, Bergman RG, Arnold J. Dis-assembly of a benzylic CF3 group mediated by a niobium(III) imido complex. J Am Chem Soc. 2013 Jun 05; 135(22):8145-8. PMID: 23663120.
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      32. Gianetti TL, Nocton G, Minasian SG, Tomson NC, Kilcoyne AL, Kozimor SA, Shuh DK, Tyliszczak T, Bergman RG, Arnold J. Diniobium inverted sandwich complexes with µ-?6:?6-arene ligands: synthesis, kinetics of formation, and electronic structure. J Am Chem Soc. 2013 Feb 27; 135(8):3224-36. PMID: 23343247.
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      33. Minasian SG, Krinsky JL, Arnold J. Evaluating f-element bonding from structure and thermodynamics. Chemistry. 2011 Oct 24; 17(44):12234-45. PMID: 21953542.
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      34. Gianetti TL, Tomson NC, Arnold J, Bergman RG. Z-selective, catalytic internal alkyne semihydrogenation under H2/CO mixtures by a niobium(III) imido complex. J Am Chem Soc. 2011 Sep 28; 133(38):14904-7. PMID: 21854008.
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      35. Rozenel SS, Kerr JB, Arnold J. Metal complexes of Co, Ni and Cu with the pincer ligand HN(CH2CH2P(i)Pr2)2: preparation, characterization and electrochemistry. Dalton Trans. 2011 Oct 28; 40(40):10397-405. PMID: 21766111.
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      36. Tomson NC, Arnold J, Bergman RG. Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and ß-diketiminato ligands. Dalton Trans. 2011 Aug 14; 40(30):7718-29. PMID: 21523303.
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      37. Krinsky JL, Minasian SG, Arnold J. Covalent lanthanide chemistry near the limit of weak bonding: observation of (CpSiMe3)3Ce-ECp* and a comprehensive density functional theory analysis of Cp3Ln-ECp (E = Al, Ga). Inorg Chem. 2011 Jan 03; 50(1):345-57. PMID: 21141834.
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      38. Fischer PJ, Minasian SG, Arnold J. cis,fac-Dichlorido{N-[3,5-di-tert-butyl-2-(trimethyl-silyl-oxy)benz-yl]-N,N-bis-(2-pyridylmeth-yl)amine}(dimethyl sulfoxide)ruthenium(II) dichloro-methane disolvate. Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 17; 65(Pt 11):m1371-2. PMID: 21578123; PMCID: PMC2971178.
      39. Minasian SG, Krinsky JL, Rinehart JD, Copping R, Tyliszczak T, Janousch M, Shuh DK, Arnold J. A comparison of 4f vs 5f metal-metal bonds in (CpSiMe3)3M-ECp* (M = Nd, U; E = Al, Ga; Cp* = C5Me5): synthesis, thermodynamics, magnetism, and electronic structure. J Am Chem Soc. 2009 Sep 30; 131(38):13767-83. PMID: 19725526.
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      40. Chomitz WA, Arnold J. Substitution and reaction chemistry of cobalt complexes supported by [N2P2] ligands. Inorg Chem. 2009 Apr 06; 48(7):3274-86. PMID: 19260662.
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      41. Chomitz WA, Arnold J. Synthesis and characterization of manganese and iron complexes supported by multidentate [N2P2] ligands. Dalton Trans. 2009 Mar 14; (10):1714-20. PMID: 19240904.
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      42. Chomitz WA, Arnold J. Use of tetradentate monoanionic ligands for stabilizing reactive metal complexes. Chemistry. 2009; 15(9):2020-30. PMID: 19160435.
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      43. Minasian SG, Arnold J. Aluminium, zinc, gallium, and cadmium complexes supported by a monoanionic [N2P2] ligand. Dalton Trans. 2009 Jan 07; (1):106-10. PMID: 19081977.
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      44. Tomson NC, Yan A, Arnold J, Bergman RG. An unusally diverse array of products formed upon carbonylation of a dialkylniobium complex. J Am Chem Soc. 2008 Aug 27; 130(34):11262-3. PMID: 18671347; PMCID: PMC2556956.
      45. Minasian SG, Arnold J. Synthesis and reactivity of bis-pentamethylcyclopentadienyl diiododialane (Cp*AlI)2: an aluminium(II) precursor to (Cp*Al)4. Chem Commun (Camb). 2008 Sep 14; (34):4043-5. PMID: 18758620.
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      46. Minasian SG, Krinsky JL, Williams VA, Arnold J. A heterobimetallic complex with an unsupported uranium(III)-aluminum(I) bond: (CpSiMe3)3U-AlCp* (Cp* = C5Me5). J Am Chem Soc. 2008 Aug 06; 130(31):10086-7. PMID: 18616247.
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      47. Chomitz WA, Arnold J. Reactivity of a Co(I) [N(2)P(2)] complex with azides: evidence for a transient Co(III) imido species. Chem Commun (Camb). 2008 Aug 21; (31):3648-50. PMID: 18665287.
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      48. Krinsky JL, Anderson LL, Arnold J, Bergman RG. Oxygen-centered hexatantalum tetradecaimido cluster complexes. Inorg Chem. 2008 Feb 04; 47(3):1053-66. PMID: 18163614; PMCID: PMC2542945.
      49. Chomitz WA, Mickenberg SF, Arnold J. First-row transition metal-halide complexes supported by a monoanionic [N(2)P(2)] ligand. Inorg Chem. 2008 Jan 07; 47(1):373-80. PMID: 18052057.
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      50. Chomitz WA, Arnold J. Transition metal dinitrogen complexes supported by a versatile monoanionic [N2P2] ligand. Chem Commun (Camb). 2007 Dec 07; (45):4797-9. PMID: 18004445.
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      51. Chomitz WA, Minasian SG, Sutton AD, Arnold J. Synthesis and reactivity of metal complexes supported by the tetradentate monoanionic ligand bis(2-picolyl)(2-hydroxy-3,5-di-tert-butylbenzyl)amide (BPPA). Inorg Chem. 2007 Aug 20; 46(17):7199-209. PMID: 17655225.
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      52. Krinsky JL, Anderson LL, Arnold J, Bergman RG. Synthesis and properties of oxygen-centered tetradecaimido hexatantalum clusters. Angew Chem Int Ed Engl. 2007; 46(3):369-72. PMID: 17154203; PMCID: PMC2552399.
      53. Westmoreland I, Arnold J. Phenoxytriamine complexes of yttrium: synthesis, structure and use in the polymerization of lactide and epsilon-caprolactone. Dalton Trans. 2006 Sep 14; (34):4155-63. PMID: 16924293.
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      54. Mulvihill MJ, Rupert BL, He R, Hochbaum A, Arnold J, Yang P. Synthesis of bifunctional polymer nanotubes from silicon nanowire templates via atom transfer radical polymerization. J Am Chem Soc. 2005 Nov 23; 127(46):16040-1. PMID: 16287287.
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      55. Mullins SM, Bergman RG, Arnold J. Olefination and group transfer reactions of an electron deficient tantalum methylidene complex. Dalton Trans. 2006 Jan 07; (1):203-12. PMID: 16357978.
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      56. Anderson LL, Arnold J, Bergman RG. Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiency. J Am Chem Soc. 2005 Oct 26; 127(42):14542-3. PMID: 16231885; PMCID: PMC2546609.
      57. Cui C, Shafir A, Schmidt JA, Oliver AG, Arnold J. Synthesis and characterization of mono beta-diketiminatosamarium amides and hydrocarbyls. Dalton Trans. 2005 Apr 21; (8):1387-93. PMID: 15824776.
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      58. Shafir A, Fiedler D, Arnold J. Highly diastereoselective reduction of ferrocene bis-imines with methyllithium and the formation of C2-symmetric Zr complexes. Chem Commun (Camb). 2003 Oct 21; (20):2598-9. PMID: 14594299.
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      59. Schmidt JA, Giesbrecht GR, Cui C, Arnold J. Anionic triazacyclononanes: new supporting ligands in main group and transition metal organometallic chemistry. Chem Commun (Camb). 2003 May 07; (9):1025-33. PMID: 12772888.
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