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Frei, Heinz

TitleChemist Sr Staff Sci/Engr
InstitutionLawrence Berkeley National Lab
DepartmentMolecular Biophys & Integ Bio
Address1 Cyclotron Road
Berkeley CA 94720
Phone510/486-4325
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    Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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    1. Sheng H, Oh MH, Osowiecki WT, Kim W, Alivisatos AP, Frei H. Carbon Dioxide Dimer Radical Anion as Surface Intermediate of Photoinduced CO2 Reduction at Aqueous Cu and CdSe Nanoparticle Catalysts by Rapid-Scan FT-IR Spectroscopy. J Am Chem Soc. 2018 Mar 28; 140(12):4363-4371. PMID: 29522319.
      View in: PubMed
    2. Edri E, Aloni S, Frei H. Fabrication of Core-Shell Nanotube Array for Artificial Photosynthesis Featuring an Ultrathin Composite Separation Membrane. ACS Nano. 2018 Jan 23; 12(1):533-541. PMID: 29294285.
      View in: PubMed
    3. Edri E, Cooper JK, Sharp ID, Guldi DM, Frei H. Ultrafast Charge Transfer between Light Absorber and Co3O4 Water Oxidation Catalyst across Molecular Wires Embedded in Silica Membrane. J Am Chem Soc. 2017 04 19; 139(15):5458-5466. PMID: 28355079.
      View in: PubMed
    4. Zhang M, Frei H. Water Oxidation Mechanisms of Metal Oxide Catalysts by Vibrational Spectroscopy of Transient Intermediates. Annu Rev Phys Chem. 2017 05 05; 68:209-231. PMID: 28226220.
      View in: PubMed
    5. Kim W, Edri E, Frei H. Hierarchical Inorganic Assemblies for Artificial Photosynthesis. Acc Chem Res. 2016 Sep 20; 49(9):1634-45. PMID: 27575376.
      View in: PubMed
    6. Sheng H, Frei H. Direct Observation by Rapid-Scan FT-IR Spectroscopy of Two-Electron-Reduced Intermediate of Tetraaza Catalyst [Co(II)N4H(MeCN)](2+) Converting CO2 to CO. J Am Chem Soc. 2016 08 10; 138(31):9959-67. PMID: 27420191.
      View in: PubMed
    7. Kim W, McClure BA, Edri E, Frei H. Coupling carbon dioxide reduction with water oxidation in nanoscale photocatalytic assemblies. Chem Soc Rev. 2016 06 07; 45(11):3221-43. PMID: 27121982.
      View in: PubMed
    8. Maier J, Liu P, Hu X, Stucky G, Sun SG, Chen L, Han W, Whang DR, Chen G, Zhan C, He J, Cronin L, Yang S, Reisner E, Long L, Mount A, Seshadri R, Yang X, Pan F, Liu H, Li Z, Tian Z, Frei H, Luo J, Li F, Du P, Wang B, Li Y, Zhao Y, Sun L, Hisatomi T, Li C, Zhu K, Park NG, Wang H, Gr├Ątzel M. Solar cells and photocatalytic systems: general discussion. Faraday Discuss. 2014; 176:313-31. PMID: 25697567.
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    9. Mount A, Xiong S, Shan X, Lee HW, Yu X, Chao Y, Stucky G, Chen G, Qi Z, Hutchings G, Zhong Y, Holze R, Han W, Cronin L, Yang S, Li H, Hong X, Reisner E, Yang Y, Xuan W, Grey C, Seshadri R, Mai L, Xie J, Pan F, Li Z, Maier J, Tian Z, Chen Y, Mao B, Frei H, Lin C, Liao F, Liu D, Zheng N, Lin R, Vannier RN, Deng D, M Griffin J, Markovic N, Zheng H, Kanno R. Electrochemical conversion and storage systems: general discussion. Faraday Discuss. 2014; 176:153-84. PMID: 25699523.
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    10. Yuan G, Agiral A, Pellet N, Kim W, Frei H. Inorganic core-shell assemblies for closing the artificial photosynthetic cycle. Faraday Discuss. 2014; 176:233-49. PMID: 25430968.
      View in: PubMed
    11. Kim W, Yuan G, McClure BA, Frei H. Light induced carbon dioxide reduction by water at binuclear ZrOCo(II) unit coupled to Ir oxide nanocluster catalyst. J Am Chem Soc. 2014 Aug 06; 136(31):11034-42. PMID: 25033315.
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    12. Yang J, Walczak K, Anzenberg E, Toma FM, Yuan G, Beeman J, Schwartzberg A, Lin Y, Hettick M, Javey A, Ager JW, Yano J, Frei H, Sharp ID. Efficient and sustained photoelectrochemical water oxidation by cobalt oxide/silicon photoanodes with nanotextured interfaces. J Am Chem Soc. 2014 Apr 30; 136(17):6191-4. PMID: 24720554.
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    13. Shu XZ, Zhang M, He Y, Frei H, Toste FD. Dual visible light photoredox and gold-catalyzed arylative ring expansion. J Am Chem Soc. 2014 Apr 23; 136(16):5844-7. PMID: 24730447; PMCID: PMC4333587.
    14. Zhang M, de Respinis M, Frei H. Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst. Nat Chem. 2014 Apr; 6(4):362-7. PMID: 24651205.
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    15. Soo HS, Agiral A, Bachmeier A, Frei H. Visible light-induced hole injection into rectifying molecular wires anchored on Co3O4 and SiO2 nanoparticles. J Am Chem Soc. 2012 Oct 17; 134(41):17104-16. PMID: 22934720.
      View in: PubMed
    16. Sivasankar N, Weare WW, Frei H. Direct observation of a hydroperoxide surface intermediate upon visible light-driven water oxidation at an Ir oxide nanocluster catalyst by rapid-scan FT-IR spectroscopy. J Am Chem Soc. 2011 Aug 24; 133(33):12976-9. PMID: 21770440.
      View in: PubMed
    17. Jiao F, Frei H. Nanostructured manganese oxide clusters supported on mesoporous silica as efficient oxygen-evolving catalysts. Chem Commun (Camb). 2010 May 07; 46(17):2920-2. PMID: 20386823.
      View in: PubMed
    18. Somorjai GA, Frei H, Park JY. Advancing the frontiers in nanocatalysis, biointerfaces, and renewable energy conversion by innovations of surface techniques. J Am Chem Soc. 2009 Nov 25; 131(46):16589-605. PMID: 19919130.
      View in: PubMed
    19. Wu X, Weare WW, Frei H. Binuclear TiOMn charge-transfer chromophore in mesoporous silica. Dalton Trans. 2009 Dec 07; (45):10114-21. PMID: 19904439.
      View in: PubMed
    20. Borodko Y, Jones L, Lee H, Frei H, Somorjai G. Spectroscopic study of tetradecyltrimethylammonium bromide Pt-C14TAB nanoparticles: structure and stability. Langmuir. 2009 Jun 16; 25(12):6665-71. PMID: 19397251.
      View in: PubMed
    21. Jiao F, Frei H. Nanostructured cobalt oxide clusters in mesoporous silica as efficient oxygen-evolving catalysts. Angew Chem Int Ed Engl. 2009; 48(10):1841-4. PMID: 19173364.
      View in: PubMed
    22. Weare WW, Pushkar Y, Yachandra VK, Frei H. Visible light-induced electron transfer from di-mu-oxo-bridged dinuclear Mn complexes to Cr centers in silica nanopores. J Am Chem Soc. 2008 Aug 27; 130(34):11355-63. PMID: 18665599.
      View in: PubMed
    23. Mul G, Wasylenko W, Hamdy MS, Frei H. Cyclohexene photo-oxidation over vanadia catalyst analyzed by time resolved ATR-FT-IR spectroscopy. Phys Chem Chem Phys. 2008 Jun 07; 10(21):3131-7. PMID: 18688378.
      View in: PubMed
    24. Wasylenko W, Frei H. Direct observation of the kinetically relevant site of CO hydrogenation on supported Ru catalyst at 700 K by time-resolved FT-IR spectroscopy. Phys Chem Chem Phys. 2007 Oct 28; 9(40):5497-502. PMID: 17925976.
      View in: PubMed
    25. Borodko Y, Habas SE, Koebel M, Yang P, Frei H, Somorjai GA. Probing the interaction of poly(vinylpyrrolidone) with platinum nanocrystals by UV-Raman and FTIR. J Phys Chem B. 2006 Nov 23; 110(46):23052-9. PMID: 17107143.
      View in: PubMed
    26. Andersen LK, Frei H. Dynamics of CO in mesoporous silica monitored by time-resolved step-scan and rapid-scan FT-IR spectroscopy. J Phys Chem B. 2006 Nov 16; 110(45):22601-7. PMID: 17092007.
      View in: PubMed
    27. Nakamura R, Frei H. Visible light-driven water oxidation by Ir oxide clusters coupled to single Cr centers in mesoporous silica. J Am Chem Soc. 2006 Aug 23; 128(33):10668-9. PMID: 16910647.
      View in: PubMed
    28. Frei H. Chemistry. Selective hydrocarbon oxidation in zeolites. Science. 2006 Jul 21; 313(5785):309-10. PMID: 16857928.
      View in: PubMed
    29. Cahoon JF, Kling MF, Sawyer KR, Frei H, Harris CB. 19-electron intermediates in the ligand substitution of CpW(CO)3* with a Lewis base. J Am Chem Soc. 2006 Mar 15; 128(10):3152-3. PMID: 16522089.
      View in: PubMed
    30. Wasylenko W, Frei H. Direct observation of surface ethyl to ethane interconversion upon C2H4 hydrogenation over Pt/Al2O3 catalyst by time-resolved FT-IR spectroscopy. J Phys Chem B. 2005 Sep 08; 109(35):16873-8. PMID: 16853147.
      View in: PubMed
    31. Lin W, Frei H. Anchored metal-to-metal charge-transfer chromophores in a mesoporous silicate sieve for visible-light activation of titanium centers. J Phys Chem B. 2005 Mar 24; 109(11):4929-35. PMID: 16863149.
      View in: PubMed
    32. Lin W, Frei H. Photochemical CO2 splitting by metal-to-metal charge-transfer excitation in mesoporous ZrCu(I)-MCM-41 silicate sieve. J Am Chem Soc. 2005 Feb 16; 127(6):1610-1. PMID: 15700974.
      View in: PubMed
    33. Asplund MC, Snee PT, Yeston JS, Wilkens MJ, Payne CK, Yang H, Kotz KT, Frei H, Bergman RG, Harris CB. Ultrafast UV pump/IR probe studies of C-H activation in linear, cyclic, and aryl hydrocarbons. J Am Chem Soc. 2002 Sep 04; 124(35):10605-12. PMID: 12197763.
      View in: PubMed
    34. Lin W, Frei H. Photochemical and FT-IR probing of the active site of hydrogen peroxide in Ti silicalite sieve. J Am Chem Soc. 2002 Aug 07; 124(31):9292-8. PMID: 12149037.
      View in: PubMed
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