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    Frei, Heinz

    TitleChemist Sr Staff Sci/Engr
    SchoolLawrence Berkeley National Lab
    DepartmentMolecular Biophys & Integ Bio
    Address1 Cyclotron Road
    Berkeley CA 94720
    Phone510/486-4325
    vCardDownload vCard

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      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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      1. Edri E, Aloni S, Frei H. Fabrication of Core-Shell Nanotube Array for Artificial Photosynthesis Featuring an Ultrathin Composite Separation Membrane. ACS Nano. 2018 Jan 09. PMID: 29294285.
        View in: PubMed
      2. Edri E, Cooper JK, Sharp ID, Guldi DM, Frei H. Ultrafast Charge Transfer Between Light Absorber and Co3O4 Water Oxidation Catalyst Across Molecular Wires Embedded in Silica Membrane. J Am Chem Soc. 2017 Mar 29. PMID: 28355079.
        View in: PubMed
      3. Zhang M, Frei H. Water Oxidation Mechanisms of Metal Oxide Catalysts by Vibrational Spectroscopy of Transient Intermediates. Annu Rev Phys Chem. 2017 May 05; 68:209-231. PMID: 28226220.
        View in: PubMed
      4. Alonso-Mori R, Asa K, Bergmann U, Brewster AS, Chatterjee R, Cooper JK, Frei H, Fuller FD, Goggins E, Gul S, Fukuzawa H, Iablonskyi D, Ibrahim M, Katayama T, Kroll T, Kumagai Y, McClure BA, Messinger J, Motomura K, Nagaya K, Nishiyama T, Saracini C, Sato Y, Sauter NK, Sokaras D, Takanashi T, Togashi T, Ueda K, Weare WW, Weng TC, Yabashi M, Yachandra VK, Young ID, Zouni A, Kern JF, Yano J. Towards characterization of photo-excited electron transfer and catalysis in natural and artificial systems using XFELs. Faraday Discuss. 2016 Dec 16; 194:621-638. PMID: 27711803.
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      5. Kisielowski C, Frei H, Specht P, Sharp ID, Haber JA, Helveg S. Detecting structural variances of Co3O4 catalysts by controlling beam-induced sample alterations in the vacuum of a transmission electron microscope. Adv Struct Chem Imaging. 2017; 2(1):13. PMID: 27867836.
        View in: PubMed
      6. Kim W, Edri E, Frei H. Hierarchical Inorganic Assemblies for Artificial Photosynthesis. Acc Chem Res. 2016 Sep 20; 49(9):1634-45. PMID: 27575376.
        View in: PubMed
      7. Sheng H, Frei H. Direct Observation by Rapid-Scan FT-IR Spectroscopy of Two-Electron-Reduced Intermediate of Tetraaza Catalyst [Co(II)N4H(MeCN)](2+) Converting CO2 to CO. J Am Chem Soc. 2016 Aug 10; 138(31):9959-67. PMID: 27420191.
        View in: PubMed
      8. Kim W, McClure BA, Edri E, Frei H. Coupling carbon dioxide reduction with water oxidation in nanoscale photocatalytic assemblies. Chem Soc Rev. 2016 06 07; 45(11):3221-43. PMID: 27121982.
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      9. Maier J, Liu P, Hu X, Stucky G, Sun SG, Chen L, Han W, Whang DR, Chen G, Zhan C, He J, Cronin L, Yang S, Reisner E, Long L, Mount A, Seshadri R, Yang X, Pan F, Liu H, Li Z, Tian Z, Frei H, Luo J, Li F, Du P, Wang B, Li Y, Zhao Y, Sun L, Hisatomi T, Li C, Zhu K, Park NG, Wang H, Gr├Ątzel M. Solar cells and photocatalytic systems: general discussion. Faraday Discuss. 2014; 176:313-31. PMID: 25697567.
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      10. Mount A, Xiong S, Shan X, Lee HW, Yu X, Chao Y, Stucky G, Chen G, Qi Z, Hutchings G, Zhong Y, Holze R, Han W, Cronin L, Yang S, Li H, Hong X, Reisner E, Yang Y, Xuan W, Grey C, Seshadri R, Mai L, Xie J, Pan F, Li Z, Maier J, Tian Z, Chen Y, Mao B, Frei H, Lin C, Liao F, Liu D, Zheng N, Lin R, Vannier RN, Deng D, M Griffin J, Markovic N, Zheng H, Kanno R. Electrochemical conversion and storage systems: general discussion. Faraday Discuss. 2014; 176:153-84. PMID: 25699523.
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      11. Yuan G, Agiral A, Pellet N, Kim W, Frei H. Inorganic core-shell assemblies for closing the artificial photosynthetic cycle. Faraday Discuss. 2014; 176:233-49. PMID: 25430968.
        View in: PubMed
      12. Kim W, Yuan G, McClure BA, Frei H. Light induced carbon dioxide reduction by water at binuclear ZrOCo(II) unit coupled to Ir oxide nanocluster catalyst. J Am Chem Soc. 2014 Aug 06; 136(31):11034-42. PMID: 25033315.
        View in: PubMed
      13. Yang J, Walczak K, Anzenberg E, Toma FM, Yuan G, Beeman J, Schwartzberg A, Lin Y, Hettick M, Javey A, Ager JW, Yano J, Frei H, Sharp ID. Efficient and sustained photoelectrochemical water oxidation by cobalt oxide/silicon photoanodes with nanotextured interfaces. J Am Chem Soc. 2014 Apr 30; 136(17):6191-4. PMID: 24720554.
        View in: PubMed
      14. Shu XZ, Zhang M, He Y, Frei H, Toste FD. Dual visible light photoredox and gold-catalyzed arylative ring expansion. J Am Chem Soc. 2014 Apr 23; 136(16):5844-7. PMID: 24730447; PMCID: PMC4333587.
      15. Zhang M, de Respinis M, Frei H. Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst. Nat Chem. 2014 Apr; 6(4):362-7. PMID: 24651205.
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      16. Soo HS, Agiral A, Bachmeier A, Frei H. Visible light-induced hole injection into rectifying molecular wires anchored on Co3O4 and SiO2 nanoparticles. J Am Chem Soc. 2012 Oct 17; 134(41):17104-16. PMID: 22934720.
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      17. Sivasankar N, Weare WW, Frei H. Direct observation of a hydroperoxide surface intermediate upon visible light-driven water oxidation at an Ir oxide nanocluster catalyst by rapid-scan FT-IR spectroscopy. J Am Chem Soc. 2011 Aug 24; 133(33):12976-9. PMID: 21770440.
        View in: PubMed
      18. Jiao F, Frei H. Nanostructured manganese oxide clusters supported on mesoporous silica as efficient oxygen-evolving catalysts. Chem Commun (Camb). 2010 May 07; 46(17):2920-2. PMID: 20386823.
        View in: PubMed
      19. Somorjai GA, Frei H, Park JY. Advancing the frontiers in nanocatalysis, biointerfaces, and renewable energy conversion by innovations of surface techniques. J Am Chem Soc. 2009 Nov 25; 131(46):16589-605. PMID: 19919130.
        View in: PubMed
      20. Wu X, Weare WW, Frei H. Binuclear TiOMn charge-transfer chromophore in mesoporous silica. Dalton Trans. 2009 Dec 07; (45):10114-21. PMID: 19904439.
        View in: PubMed
      21. Borodko Y, Jones L, Lee H, Frei H, Somorjai G. Spectroscopic study of tetradecyltrimethylammonium bromide Pt-C14TAB nanoparticles: structure and stability. Langmuir. 2009 Jun 16; 25(12):6665-71. PMID: 19397251.
        View in: PubMed
      22. Jiao F, Frei H. Nanostructured cobalt oxide clusters in mesoporous silica as efficient oxygen-evolving catalysts. Angew Chem Int Ed Engl. 2009; 48(10):1841-4. PMID: 19173364.
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      23. Weare WW, Pushkar Y, Yachandra VK, Frei H. Visible light-induced electron transfer from di-mu-oxo-bridged dinuclear Mn complexes to Cr centers in silica nanopores. J Am Chem Soc. 2008 Aug 27; 130(34):11355-63. PMID: 18665599.
        View in: PubMed
      24. Mul G, Wasylenko W, Hamdy MS, Frei H. Cyclohexene photo-oxidation over vanadia catalyst analyzed by time resolved ATR-FT-IR spectroscopy. Phys Chem Chem Phys. 2008 Jun 07; 10(21):3131-7. PMID: 18688378.
        View in: PubMed
      25. Wasylenko W, Frei H. Direct observation of the kinetically relevant site of CO hydrogenation on supported Ru catalyst at 700 K by time-resolved FT-IR spectroscopy. Phys Chem Chem Phys. 2007 Oct 28; 9(40):5497-502. PMID: 17925976.
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      26. Borodko Y, Habas SE, Koebel M, Yang P, Frei H, Somorjai GA. Probing the interaction of poly(vinylpyrrolidone) with platinum nanocrystals by UV-Raman and FTIR. J Phys Chem B. 2006 Nov 23; 110(46):23052-9. PMID: 17107143.
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      27. Andersen LK, Frei H. Dynamics of CO in mesoporous silica monitored by time-resolved step-scan and rapid-scan FT-IR spectroscopy. J Phys Chem B. 2006 Nov 16; 110(45):22601-7. PMID: 17092007.
        View in: PubMed
      28. Nakamura R, Frei H. Visible light-driven water oxidation by Ir oxide clusters coupled to single Cr centers in mesoporous silica. J Am Chem Soc. 2006 Aug 23; 128(33):10668-9. PMID: 16910647.
        View in: PubMed
      29. Frei H. Chemistry. Selective hydrocarbon oxidation in zeolites. Science. 2006 Jul 21; 313(5785):309-10. PMID: 16857928.
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      30. Cahoon JF, Kling MF, Sawyer KR, Frei H, Harris CB. 19-electron intermediates in the ligand substitution of CpW(CO)3* with a Lewis base. J Am Chem Soc. 2006 Mar 15; 128(10):3152-3. PMID: 16522089.
        View in: PubMed
      31. Wasylenko W, Frei H. Direct observation of surface ethyl to ethane interconversion upon C2H4 hydrogenation over Pt/Al2O3 catalyst by time-resolved FT-IR spectroscopy. J Phys Chem B. 2005 Sep 08; 109(35):16873-8. PMID: 16853147.
        View in: PubMed
      32. Lin W, Frei H. Anchored metal-to-metal charge-transfer chromophores in a mesoporous silicate sieve for visible-light activation of titanium centers. J Phys Chem B. 2005 Mar 24; 109(11):4929-35. PMID: 16863149.
        View in: PubMed
      33. Lin W, Frei H. Photochemical CO2 splitting by metal-to-metal charge-transfer excitation in mesoporous ZrCu(I)-MCM-41 silicate sieve. J Am Chem Soc. 2005 Feb 16; 127(6):1610-1. PMID: 15700974.
        View in: PubMed
      34. Asplund MC, Snee PT, Yeston JS, Wilkens MJ, Payne CK, Yang H, Kotz KT, Frei H, Bergman RG, Harris CB. Ultrafast UV pump/IR probe studies of C-H activation in linear, cyclic, and aryl hydrocarbons. J Am Chem Soc. 2002 Sep 04; 124(35):10605-12. PMID: 12197763.
        View in: PubMed
      35. Lin W, Frei H. Photochemical and FT-IR probing of the active site of hydrogen peroxide in Ti silicalite sieve. J Am Chem Soc. 2002 Aug 07; 124(31):9292-8. PMID: 12149037.
        View in: PubMed
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