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    Tilley, T Don

    TitleChemist Senior Faculty
    SchoolLawrence Berkeley National Lab
    DepartmentChemical Sciences
    Address1 Cyclotron Road
    Berkeley CA 94720
    Phone510/642-8939
    vCardDownload vCard

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      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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      1. Nguyen AI, Suess DLM, Darago LE, Oyala PH, Levine DS, Ziegler MS, Britt RD, Tilley T. Manganese-Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts. J Am Chem Soc. 2017 Apr 19; 139(15):5579-5587. PMID: 28347135.
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      2. Kiel GR, Ziegler MS, Tilley T. Zirconacyclopentadiene-Annulated Polycyclic Aromatic Hydrocarbons. Angew Chem Int Ed Engl. 2017 Apr 18; 56(17):4839-4844. PMID: 28334480.
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      3. Lipke MC, Liberman-Martin AL, Tilley T. Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations. Angew Chem Int Ed Engl. 2017 Feb 20; 56(9):2260-2294. PMID: 27641142.
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      4. Dombrowski JP, Johnson GR, Bell AT, Tilley T. Correction: Ga[OSi(OtBu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. Dalton Trans. 2016 Nov 22; 45(46):18750-18751. PMID: 27834429.
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      5. Lipke MC, Liberman-Martin AL, Tilley T. Significant Cooperativity Between Ruthenium and Silicon in Catalytic Transformations of an Isocyanide. J Am Chem Soc. 2016 Aug 03; 138(30):9704-13. PMID: 27384746.
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      6. Dombrowski JP, Johnson GR, Bell AT, Tilley T. Ga[OSi(O(t)Bu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. Dalton Trans. 2016 Jul 05; 45(27):11025-34. PMID: 27312519.
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      7. Liberman-Martin AL, Levine DS, Ziegler MS, Bergman RG, Tilley T. Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand. Chem Commun (Camb). 2016 May 19; 52(43):7039-42. PMID: 27161155.
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      8. Ziegler MS, Levine DS, Lakshmi KV, Tilley T. Aryl Group Transfer from Tetraarylborato Anions to an Electrophilic Dicopper(I) Center and Mixed-Valence µ-Aryl Dicopper(I,II) Complexes. J Am Chem Soc. 2016 May 25; 138(20):6484-91. PMID: 27176131.
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      9. Dong Y, Lipschutz MI, Tilley T. Regioselective, Transition Metal-Free C-O Coupling Reactions Involving Aryne Intermediates. Org Lett. 2016 Apr 01; 18(7):1530-3. PMID: 27010921.
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      10. Panetier JA, Letko CS, Tilley T, Head-Gordon M. Computational Characterization of Redox Non-Innocence in Cobalt-Bis(Diaryldithiolene)-Catalyzed Proton Reduction. J Chem Theory Comput. 2016 Jan 12; 12(1):223-30. PMID: 26598074.
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      11. Nguyen AI, Ziegler MS, Oña-Burgos P, Sturzbecher-Hohne M, Kim W, Bellone DE, Tilley T. Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation. J Am Chem Soc. 2015 Oct 14; 137(40):12865-72. PMID: 26390993.
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      12. Liu HJ, Landis C, Raynaud C, Eisenstein O, Tilley T. Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes. J Am Chem Soc. 2015 Jul 22; 137(28):9186-94. PMID: 26135519.
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      13. Lipschutz MI, Chantarojsiri T, Dong Y, Tilley T. Synthesis, characterization, and alkyne trimerization catalysis of a heteroleptic two-coordinate fe(i) complex. J Am Chem Soc. 2015 May 20; 137(19):6366-72. PMID: 25928273.
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      14. Liberman-Martin AL, Bergman RG, Tilley T. Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. J Am Chem Soc. 2015 Apr 29; 137(16):5328-31. PMID: 25879515; PMCID: PMC4428610.
      15. Liu HJ, Ziegler MS, Tilley T. The Ruthenostannylene Complex [Cp*(IXy)H2 Ru-Sn-Trip]: Providing Access to Unusual Ru-Sn Bonded Stanna-imine, Stannene, and Ketenylstannyl Complexes. Angew Chem Int Ed Engl. 2015 May 26; 54(22):6622-6. PMID: 25845838.
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      16. Van Allsburg KM, Anzenberg E, Drisdell WS, Yano J, Tilley T. Oxygen-atom transfer chemistry and thermolytic properties of a di-tert-butylphosphate-ligated Mn4O4 cubane. Chemistry. 2015 Mar 16; 21(12):4646-54. PMID: 25676196.
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      17. Liu W, Tilley T. Sterically controlled functionalization of carbon surfaces with -C6H4CH2X (X = OSO2Me or N3) groups for surface attachment of redox-active molecules. Langmuir. 2015 Jan 27; 31(3):1189-95. PMID: 25549529.
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      18. Arnold J, Brothers PJ, Mountford P, Piers WE, Thomas CM, Tilley T. The influence of Michael Lappert on the chemistry landscape. Dalton Trans. 2014 Nov 28; 43(44):16553-6. PMID: 25331627.
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      19. Lipke MC, Tilley T. Hypercoordinate ketone adducts of electrophilic ?3-H2SiRR' ligands on ruthenium as key intermediates for efficient and robust catalytic hydrosilation. J Am Chem Soc. 2014 Nov 19; 136(46):16387-98. PMID: 25347044.
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      20. Cai IC, Lipschutz MI, Tilley T. A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states. Chem Commun (Camb). 2014 Nov 07; 50(86):13062-5. PMID: 25222516; PMCID: PMC4184985.
      21. Lipschutz MI, Tilley T. Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6- i Pr2-C6H3)]2} Organometallics. 2014 Oct 13; 33(19):5566-5570. PMID: 25328273.
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      22. Liu HJ, Guihaumé J, Davin T, Raynaud C, Eisenstein O, Tilley T. 1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion. J Am Chem Soc. 2014 Oct 08; 136(40):13991-4. PMID: 25247392.
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      23. Liu HJ, Raynaud C, Eisenstein O, Tilley T. Cyclometalated N-heterocyclic carbene complexes of ruthenium for access to electron-rich silylene complexes that bind the Lewis acids CuOTf and AgOTf. J Am Chem Soc. 2014 Aug 13; 136(32):11473-82. PMID: 25050912.
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      24. Nguyen AI, Hadt RG, Solomon EI, Tilley T. Efficient C-H Bond Activations via O2 Cleavage by a Dianionic Cobalt(II) Complex. Chem Sci. 2014 Jul 01; 5(7):2874-2878. PMID: 25071930.
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      25. Letko CS, Panetier JA, Head-Gordon M, Tilley T. Mechanism of the electrocatalytic reduction of protons with diaryldithiolene cobalt complexes. J Am Chem Soc. 2014 Jul 02; 136(26):9364-76. PMID: 24950387.
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      26. Davenport TC, Ahn HS, Ziegler MS, Tilley T. A molecular structural analog of proposed dinuclear active sites in cobalt-based water oxidation catalysts. Chem Commun (Camb). 2014 Jun 18; 50(48):6326-9. PMID: 24797957.
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      27. Lipschutz MI, Tilley T. Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediates. Angew Chem Int Ed Engl. 2014 Jul 07; 53(28):7290-4. PMID: 24889777; PMCID: PMC4188420.
      28. Lipke MC, Neumeyer F, Tilley T. Interconversion of ?3-H2SiRR' s-complexes and 16-electron silylene complexes via reversible H-H or C-H elimination. J Am Chem Soc. 2014 Apr 23; 136(16):6092-102. PMID: 24666100.
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      29. Ahn HS, Davenport TC, Tilley T. Molecular cobalt electrocatalyst for proton reduction at low overpotential. Chem Commun (Camb). 2014 Apr 14; 50(29):3834-7. PMID: 24589710.
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      30. Liu W, Sharp ID, Tilley T. Multifunctional silicon surfaces: reaction of dichlorocarbene generated from Seyferth reagent with hydrogen-terminated silicon (111) surfaces. Langmuir. 2014 Jan 14; 30(1):172-8. PMID: 24328351.
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      31. Lipschutz MI, Yang X, Chatterjee R, Tilley T. A structurally rigid bis(amido) ligand framework in low-coordinate Ni(I), Ni(II), and Ni(III) analogues provides access to a Ni(III) methyl complex via oxidative addition. J Am Chem Soc. 2013 Oct 16; 135(41):15298-301. PMID: 24079707.
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      32. Bowring MA, Bergman RG, Tilley T. Pt-catalyzed C-C activation induced by C-H activation. J Am Chem Soc. 2013 Sep 04; 135(35):13121-8. PMID: 23962182.
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      33. Hayes PG, Xu Z, Beddie C, Keith JM, Hall MB, Tilley T. The osmium-silicon triple bond: synthesis, characterization, and reactivity of an osmium silylyne complex. J Am Chem Soc. 2013 Aug 14; 135(32):11780-3. PMID: 23906040.
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      34. Rumberger EM, Ahn HS, Bell AT, Tilley T. Water oxidation catalysis via immobilization of the dimanganese complex [Mn2(µ-O)2Cl(µ-O2CCH3)(bpy)2(H2O)](NO3)2 onto silica. Dalton Trans. 2013 Sep 14; 42(34):12238-47. PMID: 23861177.
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      35. Lipke MC, Tilley T. Silane-isocyanide coupling involving 1,1-insertion of XylNC into the Si-H bond of a s-silane ligand. J Am Chem Soc. 2013 Jul 17; 135(28):10298-301. PMID: 23834657.
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      36. Liberman-Martin AL, Bergman RG, Tilley T. A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex. J Am Chem Soc. 2013 Jul 03; 135(26):9612-5. PMID: 23789917.
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      37. Guillo P, Fasulo ME, Lipschutz MI, Tilley T. Synthesis and characterization of tantalum silsesquioxane complexes. Dalton Trans. 2013 Feb 14; 42(6):1991-5. PMID: 23283146.
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      38. Lipke MC, Tilley T. Stabilization of ArSiH4(-) and SiH6(2-) anions in diruthenium Si-H s-complexes. Angew Chem Int Ed Engl. 2012 Oct 29; 51(44):11115-21. PMID: 23037588.
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      39. Fasulo ME, Tilley T. Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(=GeRR')]+. Chem Commun (Camb). 2012 Aug 11; 48(62):7690-2. PMID: 22740052.
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      40. Lipschutz MI, Tilley T. Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex. Chem Commun (Camb). 2012 Jul 21; 48(57):7146-8. PMID: 22692366.
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      41. Yee SK, Sun J, Darancet P, Tilley T, Majumdar A, Neaton JB, Segalman RA. Inverse rectification in donor-acceptor molecular heterojunctions. ACS Nano. 2011 Nov 22; 5(11):9256-63. PMID: 22010940.
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      42. Davenport TC, Tilley T. Dinucleating naphthyridine-based ligand for assembly of bridged dicopper(I) centers: three-center two-electron bonding involving an acetonitrile donor. Angew Chem Int Ed Engl. 2011 Dec 16; 50(51):12205-8. PMID: 22038762.
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      43. Wright RJ, Zhang W, Yang X, Fasulo M, Tilley T. Isolation, observation, and computational modeling of proposed intermediates in catalytic proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4. Dalton Trans. 2012 Jan 07; 41(1):73-82. PMID: 22031098.
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      44. Curley JJ, Bergman RG, Tilley T. Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf). Dalton Trans. 2012 Jan 07; 41(1):192-200. PMID: 22020701.
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      45. Chou NH, Ross PN, Bell AT, Tilley T. Comparison of cobalt-based nanoparticles as electrocatalysts for water oxidation. ChemSusChem. 2011 Nov 18; 4(11):1566-9. PMID: 21997965.
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      46. Lipke MC, Tilley T. High electrophilicity at silicon in ?3-silane s-complexes: Lewis base adducts of a silane ligand, featuring octahedral silicon and three Ru-H-Si interactions. J Am Chem Soc. 2011 Oct 19; 133(41):16374-7. PMID: 21936540.
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      47. Cordeiro PJ, Tilley T. Enhancement of epoxidation efficiencies for Ta-SBA15 catalysts. The influence of modification with -EMe3 (E = Si, Ge, Sn) groups. Langmuir. 2011 May 17; 27(10):6295-304. PMID: 21517024.
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      48. Gessner VH, Tannaci JF, Miller AD, Tilley T. Assembly of macrocycles by zirconocene-mediated, reversible carbon-carbon bond formation. Acc Chem Res. 2011 Jun 21; 44(6):435-46. PMID: 21473633.
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      49. Roggan S, Limberg C, Knispel C, Tilley T. Transition metal complexes of the novel hexadentate ligand 1,4-bis(di(N-methylimidazol-2-yl)methyl)phthalazine. Dalton Trans. 2011 Apr 28; 40(16):4315-23. PMID: 21409278.
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      50. Gessner VH, Tilley T. Diphenylanthracene macrocylces from reductive zirconocene coupling: on the edge of steric overload. Org Lett. 2011 Mar 04; 13(5):1154-7. PMID: 21288005.
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      51. Yang J, Tilley T. Efficient hydrosilylation of carbonyl compounds with the simple amide catalyst [Fe{N(SiMe3)2}2]. Angew Chem Int Ed Engl. 2010 Dec 27; 49(52):10186-8. PMID: 20949580.
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      52. Kachian JS, Tannaci J, Wright RJ, Tilley T, Bent SF. Disulfide passivation of the Ge(100)-2 × 1 surface. Langmuir. 2011 Jan 04; 27(1):179-86. PMID: 21141841.
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      53. Levi ZU, Tilley T. Synthesis and electronic properties of extended, fused-ring aromatic systems containing multiple pentalene units. J Am Chem Soc. 2010 Aug 18; 132(32):11012-4. PMID: 20698660.
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      54. Calimano E, Tilley T. Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported by a phenyl-substituted PNP pincer ligand. Dalton Trans. 2010 Oct 21; 39(39):9250-63. PMID: 20401366.
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      55. Geramita K, Tao Y, Segalman RA, Tilley T. Synthesis and characterization of fluorinated heterofluorene-containing donor-acceptor systems. J Org Chem. 2010 Mar 19; 75(6):1871-87. PMID: 20196535.
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      56. Guihaumé J, Raynaud C, Eisenstein O, Perrin L, Maron L, Tilley T. Facile interconversion of [Cp2(Cl)Hf(SnH3)] and [Cp2(Cl)Hf(mu-H)SnH2]: DFT investigations of hafnocene stannyl complexes as masked stannylenes. Angew Chem Int Ed Engl. 2010 Mar 01; 49(10):1816-9. PMID: 20135660.
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      57. Tao C, Sun J, Zhang X, Yamachika R, Wegner D, Bahri Y, Samsonidze G, Cohen ML, Louie SG, Tilley T, Segalman RA, Crommie MF. Spatial resolution of a type II heterojunction in a single bipolar molecule. Nano Lett. 2009 Dec; 9(12):3963-7. PMID: 19904920.
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      58. Vignolle J, Tilley T. N-heterocyclic carbene-stabilized gold nanoparticles and their assembly into 3D superlattices. Chem Commun (Camb). 2009 Dec 14; (46):7230-2. PMID: 19921039.
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      59. Malen JA, Doak P, Baheti K, Tilley T, Majumdar A, Segalman RA. The nature of transport variations in molecular heterojunction electronics. Nano Lett. 2009 Oct; 9(10):3406-12. PMID: 19711966.
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      60. McBee JL, Escalada J, Tilley T. High oxidation state rhodium and iridium bis(silyl)dihydride complexes supported by a chelating pyridyl-pyrrolide ligand. J Am Chem Soc. 2009 Sep 09; 131(35):12703-13. PMID: 19681602.
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      61. Shinohara A, McBee J, Tilley T. Germylene and silylene complexes of molybdenum via E-H (E = Ge, Si) bond activations: steric influences on intramolecular MoH...E interactions. Inorg Chem. 2009 Sep 07; 48(17):8081-3. PMID: 19630379.
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      62. Wright RJ, Lim C, Tilley T. Diiron proton reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-dithiolate ligands. Chemistry. 2009 Aug 24; 15(34):8518-25. PMID: 19575350.
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      63. Calimano E, Tilley T. Synthesis and structure of PNP-supported iridium silyl and silylene complexes: catalytic hydrosilation of alkenes. J Am Chem Soc. 2009 Aug 12; 131(31):11161-73. PMID: 19603748.
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      64. Hayes PG, Gribble CW, Waterman R, Tilley T. A hydrogen-substituted osmium stannylene complex: isomerization to a metallostannylene complex via an unusual alpha-hydrogen migration from tin to osmium. J Am Chem Soc. 2009 Apr 08; 131(13):4606-7. PMID: 19290659.
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      65. Miller AD, Tannaci JF, Johnson SA, Lee H, McBee JL, Tilley T. Mesityl alkyne substituents for control of regiochemistry and reversibility in zirconocene couplings: new synthetic strategies for unsymmetrical zirconacyclopentadienes and conjugated polymers. J Am Chem Soc. 2009 Apr 08; 131(13):4917-27. PMID: 19296582.
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      66. Miller AD, McBee JL, Tilley T. Zirconocene-mediated macrocyclizations of diynes containing di-o-methylphenylene spacers. J Org Chem. 2009 Apr 03; 74(7):2880-3. PMID: 19323577.
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      67. Levi ZU, Tilley T. Versatile synthesis of pentalene derivatives via the Pd-catalyzed homocoupling of haloenynes. J Am Chem Soc. 2009 Mar 04; 131(8):2796-7. PMID: 19199434.
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      68. Malen JA, Doak P, Baheti K, Tilley T, Segalman RA, Majumdar A. Identifying the length dependence of orbital alignment and contact coupling in molecular heterojunctions. Nano Lett. 2009 Mar; 9(3):1164-9. PMID: 19239204.
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      69. Geramita K, McBee J, Tilley T. 2,7-Substituted hexafluoroheterofluorenes as potential building blocks for electron transporting materials. J Org Chem. 2009 Jan 16; 74(2):820-9. PMID: 19067545.
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      70. Huynh K, Vignolle J, Tilley T. Perfluoropentaphenylborole: a new approach to Lewis acidic, electron-deficient compounds. Angew Chem Int Ed Engl. 2009; 48(16):2835-7. PMID: 19301345.
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      71. McBee JL, Bell AT, Tilley T. Mechanistic studies of the hydroamination of norbornene with electrophilic platinum complexes: the role of proton transfer. J Am Chem Soc. 2008 Dec 10; 130(49):16562-71. PMID: 19554728.
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      72. Tannaci JF, Kratter IH, Rider EA, McBee JL, Miller AD, Tilley T. Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes. Chem Commun (Camb). 2009 Jan 08; (2):233-4. PMID: 19099079.
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      73. Geramita K, McBee J, Tao Y, Segalman RA, Tilley T. Synthesis and characterization of 2,7-bis(pentafluorophenylethynyl)hexafluoroheterofluorenes: new materials with high electron affinities. Chem Commun (Camb). 2008 Nov 07; (41):5107-9. PMID: 18956037.
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      74. Tannaci JF, Noji M, McBee JL, Tilley T. 9,10-Disubstituted octafluoroanthracene derivatives via palladium-catalyzed cross-coupling. J Org Chem. 2008 Oct 17; 73(20):7895-900. PMID: 18788782.
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      75. Ruddy DA, Tilley T. Kinetics and mechanism of olefin epoxidation with aqueous H2O2 and a highly selective surface-modified TaSBA15 heterogeneous catalyst. J Am Chem Soc. 2008 Aug 20; 130(33):11088-96. PMID: 18662001.
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      76. Calimano E, Tilley T. Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex. J Am Chem Soc. 2008 Jul 23; 130(29):9226-7. PMID: 18582049.
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      77. Miller AD, McBee JL, Tilley T. Mechanism of reversible alkyne coupling at zirconocene: ancillary ligand effects. J Am Chem Soc. 2008 Apr 09; 130(14):4992-9. PMID: 18336028.
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      78. Baheti K, Malen JA, Doak P, Reddy P, Jang SY, Tilley T, Majumdar A, Segalman RA. Probing the chemistry of molecular heterojunctions using thermoelectricity. Nano Lett. 2008 Feb; 8(2):715-9. PMID: 18269258.
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      79. Ruddy DA, Tilley T. Highly selective olefin epoxidation with aqueous H2O2 over surface-modified TaSBA15 prepared via the TMP method. Chem Commun (Camb). 2007 Aug 28; (32):3350-2. PMID: 18019495.
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      80. Tannaci JF, Noji M, McBee J, Tilley T. 9,10-Dichlorooctafluoroanthracene as a building block for n-type organic semiconductors. J Org Chem. 2007 Jul 20; 72(15):5567-73. PMID: 17590045.
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      81. Waterman R, Hayes PG, Tilley T. Synthetic development and chemical reactivity of transition-metal silylene complexes. Acc Chem Res. 2007 Aug; 40(8):712-9. PMID: 17477497.
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      82. Humphrey SM, Grass ME, Habas SE, Niesz K, Somorjai GA, Tilley T. Rhodium nanoparticles from cluster seeds: control of size and shape by precursor addition rate. Nano Lett. 2007 Mar; 7(3):785-90. PMID: 17288491.
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      83. Hoefelmeyer JD, Liu H, Somorjai GA, Tilley T. Reverse micelle synthesis of rhodium nanoparticles. J Colloid Interface Sci. 2007 May 01; 309(1):86-93. PMID: 17229435.
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      84. Waterman R, Tilley T. Antimony-antimony bond formation by reductive elimination from a hafnium bis(stibido) complex. Inorg Chem. 2006 Nov 27; 45(24):9625-7. PMID: 17112252.
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      85. Han LB, Tilley T. Selective homo- and heterodehydrocouplings of phosphines catalyzed by rhodium phosphido complexes. J Am Chem Soc. 2006 Oct 25; 128(42):13698-9. PMID: 17044692.
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      86. Waterman R, Tilley T. Terminal stibinidene ligands. Generation of CpCp*Hf=Sb(dmp) and trapping reactions with PMe3 and 2-butyne. Chem Commun (Camb). 2006 Oct 14; (38):4030-2. PMID: 17003889.
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      87. Waterman R, Tilley T. Catalytic antimony-antimony bond formation through stibinidene elimination from zirconocene and hafnocene complexes. Angew Chem Int Ed Engl. 2006 Apr 28; 45(18):2926-9. PMID: 16555350.
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      88. Hayes PG, Beddie C, Hall MB, Waterman R, Tilley T. Hydrogen-substituted osmium silylene complexes: effect of charge localization on catalytic hydrosilation. J Am Chem Soc. 2006 Jan 18; 128(2):428-9. PMID: 16402827.
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      89. Neale NR, Tilley T. Synthesis, structure, and alpha-elimination chemistry of hafnocene triarylstannyl complexes. J Am Chem Soc. 2005 Oct 26; 127(42):14745-55. PMID: 16231929.
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      90. Brutchey RL, Ruddy DA, Andersen LK, Tilley T. Influence of surface modification of Ti-SBA15 catalysts on the epoxidation mechanism for cyclohexene with aqueous hydrogen peroxide. Langmuir. 2005 Oct 11; 21(21):9576-83. PMID: 16207038.
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      91. Karshtedt D, Bell AT, Tilley T. Platinum-based catalysts for the hydroamination of olefins with sulfonamides and weakly basic anilines. J Am Chem Soc. 2005 Sep 14; 127(36):12640-6. PMID: 16144412.
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      92. Brutchey RL, Drake IJ, Bell AT, Tilley T. Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst. Chem Commun (Camb). 2005 Aug 07; (29):3736-8. PMID: 16027928.
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      93. Hoefelmeyer JD, Niesz K, Somorjai GA, Tilley T. Radial anisotropic growth of rhodium nanoparticles. Nano Lett. 2005 Mar; 5(3):435-8. PMID: 15755090.
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      94. Sadow AD, Tilley T. Synthesis and characterization of scandium silyl complexes of the type Cp*2ScSiHRR'. sigma-Bond metathesis reactions and catalytic dehydrogenative silation of hydrocarbons. J Am Chem Soc. 2005 Jan 19; 127(2):643-56. PMID: 15643889.
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      95. Krumper JR, Gerisch M, Magistrato A, Rothlisberger U, Bergman RG, Tilley T. Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure. J Am Chem Soc. 2004 Oct 06; 126(39):12492-502. PMID: 15453783.
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      96. Fujdala KL, Drake IJ, Bell AT, Tilley T. Atomic level control over surface species via a molecular precursor approach: isolated Cu(I) sites and Cu nanoparticles supported on mesoporous silica. J Am Chem Soc. 2004 Sep 08; 126(35):10864-6. PMID: 15339170.
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      97. Mork BV, Tilley T, Schultz AJ, Cowan JA. Silylene hydride complexes of molybdenum with silicon-hydrogen interactions: neutron structure of (eta(5)-C(5)Me(5))(Me(2)PCH(2)CH(2)PMe(2))Mo(H)(SiEt(2)). J Am Chem Soc. 2004 Aug 25; 126(33):10428-40. PMID: 15315459.
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      98. Jarupatrakorn J, Tilley T. Synthesis and characterization of [(diene)Rh[mu-OSi(OtBu)3]]2, a precursor to silica-bound rhodium. Dalton Trans. 2004 Sep 07; (17):2808-13. PMID: 15514769.
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      99. Gavenonis J, Tilley T. Synthesis and reactivity of tris(imido)rhenium complexes containing rhenium-main group element bonds. silicon-carbon bond activations of PhSiH(3) by silyl complexes. Inorg Chem. 2004 Jul 12; 43(14):4353-62. PMID: 15236548.
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      100. Mork BV, Tilley T. Synthons for coordinatively unsaturated complexes of tungsten, and their use for the synthesis of high oxidation-state silylene complexes. J Am Chem Soc. 2004 Apr 07; 126(13):4375-85. PMID: 15053627.
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      101. Glaser PB, Tilley T. Catalytic hydrosilylation of alkenes by a ruthenium silylene complex. Evidence for a new hydrosilylation mechanism. J Am Chem Soc. 2003 Nov 12; 125(45):13640-1. PMID: 14599184.
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      102. Sadow AD, Tilley T. Cationic hafnium silyl complexes and their enhanced reactivity in sigma-bond metathesis processes with Si-H and C-H bonds. J Am Chem Soc. 2003 Aug 06; 125(31):9462-75. PMID: 12889977.
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      103. Sadow AD, Tilley T. Homogeneous catalysis with methane. A strategy for the hydromethylation of olefins based on the nondegenerate exchange of alkyl groups and sigma-bond metathesis at scandium. J Am Chem Soc. 2003 Jul 02; 125(26):7971-7. PMID: 12823019.
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      104. Johnson SA, Liu FQ, Suh MC, Zürcher S, Haufe M, Mao SS, Tilley T. Regioselective coupling of pentafluorophenyl substituted alkynes: mechanistic insight into the zirconocene coupling of alkynes and a facile route to conjugated polymers bearing electron-withdrawing pentafluorophenyl substituents. J Am Chem Soc. 2003 Apr 09; 125(14):4199-211. PMID: 12670242.
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      105. Fujdala KL, Oliver AG, Hollander FJ, Tilley T. Tris(tert-butoxy)siloxy derivatives of boron, including the boronous acid HOB[OSi(O(t)Bu)(3)](2) and the metal (siloxy)boryloxide complex Cp(2)Zr(Me)OB[OSi(O(t)Bu)(3)](2): a remarkable crystal structure with 18 independent molecules in its asymmetric unit. Inorg Chem. 2003 Feb 24; 42(4):1140-50. PMID: 12588150.
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      106. Sadow AD, Tilley T. Catalytic functionalization of hydrocarbons by sigma-bond-metathesis chemistry: dehydrosilylation of methane with a scandium catalyst. Angew Chem Int Ed Engl. 2003 Feb 17; 42(7):803-5. PMID: 12596205.
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      107. Mork BV, Tilley T. Multiple bonding between silicon and molybdenum: a transition-metal complex with considerable silylyne character. Angew Chem Int Ed Engl. 2003 Jan 20; 42(3):357-60. PMID: 12548699.
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      108. Nozaki C, Lugmair CG, Bell AT, Tilley T. Synthesis, characterization, and catalytic performance of single-site iron(III) centers on the surface of SBA-15 silica. J Am Chem Soc. 2002 Nov 06; 124(44):13194-203. PMID: 12405848.
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      109. Gavenonis J, Tilley T. Reversible intramolecular hydride transfer between tantalum and an aromatic ring: an eta(5)-cyclohexadienyl complex as a masked hydride. J Am Chem Soc. 2002 Jul 24; 124(29):8536-7. PMID: 12121088.
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      110. Sadow AD, Tilley T. Activation of arene C[bond]H bonds by a cationic hafnium silyl complex possessing an alpha-agostic Si[bond]H interaction. J Am Chem Soc. 2002 Jun 19; 124(24):6814-5. PMID: 12059188.
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      111. Neale NR, Tilley T. A new mechanism for metal-catalyzed stannane dehydrocoupling based on alpha-H-elimination in a hafnium hydrostannyl complex. J Am Chem Soc. 2002 Apr 17; 124(15):3802-3. PMID: 11942796.
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      112. Klei SR, Golden JT, Tilley T, Bergman RG. Iridium-catalyzed H/D exchange into organic compounds in water. J Am Chem Soc. 2002 Mar 13; 124(10):2092-3. PMID: 11878944.
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      113. Schafer LL, Nitschke JR, Mao SS, Liu FQ, Harder G, Haufe M, Tilley T. Zirconocene-mediated, high-yielding macrocyclizations of silyl-terminated diynes. Chemistry. 2002 Jan 04; 8(1):74-83. PMID: 11826866.
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      114. Nitschke JR, Tilley T. Novel Templating Effect in the Macrocyclization of Functionalized Diynes by Zirconocene Coupling This work was supported by the Director, Office of Basic Energy Sciences, Chemical Sciences Division, of the U.S. Department of Energy under Contract No. DE-AC03-76SF00098. The Center for New Directions in Organic Synthesis is supported by Bristol-Myers Squibb as Sponsoring Member. We also thank Dr. F. J. Hollander of the U.C. Berkeley X-ray diffraction facility (CHEXRAY) for help with determination of the X-ray structures. Angew Chem Int Ed Engl. 2001 Jun 01; 40(11):2142-2145. PMID: 11433471.
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