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    22833 Publications
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    24 Edited Profiles

    Hartwig, John

    TitleChemist Senior Faculty SE
    SchoolLawrence Berkeley National Lab
    DepartmentChemical Sciences
    Address1 Cyclotron Road
    Berkeley CA 94720
    Phone510/642-2038

       Bibliographic 
       Publications
      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can sign in to make corrections and additions, or contact us for help.
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      1. Chen M, Hartwig JF. Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. J Am Chem Soc. 2015 Nov 4; 137(43):13972-9.
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      2. Schramm Y, Takeuchi M, Semba K, Nakao Y, Hartwig JF. Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel-N-Heterocyclic Carbene System. J Am Chem Soc. 2015 Sep 30; 137(38):12215-8.
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      3. Brusoe AT, Hartwig JF. Palladium-Catalyzed Arylation of Fluoroalkylamines. J Am Chem Soc. 2015 Jul 8; 137(26):8460-8.
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      4. Larsen MA, Wilson CV, Hartwig JF. Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity. J Am Chem Soc. 2015 Jul 8; 137(26):8633-43.
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      5. Key HM, Clark DS, Hartwig JF. Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand. J Am Chem Soc. 2015 Jul 1; 137(25):8261-8.
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      6. Lee T, Wilson TW, Berg R, Ryberg P, Hartwig JF. Rhodium-catalyzed enantioselective silylation of arene C-h bonds: desymmetrization of diarylmethanols. J Am Chem Soc. 2015 Jun 3; 137(21):6742-5.
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      7. Cheng C, Hartwig JF. Catalytic Silylation of Unactivated C-H Bonds. Chem Rev. 2015 Sep 9; 115(17):8946-75.
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      8. Green RA, Hartwig JF. Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts. Angew Chem Int Ed Engl. 2015 Mar 16; 54(12):3768-72.
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      9. Sharma A, Hartwig JF. Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization. Nature. 2015 Jan 29; 517(7536):600-4.
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      10. Cheng C, Hartwig JF. Iridium-catalyzed silylation of aryl C-h bonds. J Am Chem Soc. 2015 Jan 21; 137(2):592-5.
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      11. Tran BL, Driess M, Hartwig JF. Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes. J Am Chem Soc. 2014 Dec 10; 136(49):17292-301.
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      12. Chen W, Chen M, Hartwig JF. Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates. J Am Chem Soc. 2014 Nov 12; 136(45):15825-8.
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      13. Ge S, Arlow SI, Mormino MG, Hartwig JF. Pd-Catalyzed a-Arylation of Trimethylsilyl Enolates of a,a-Difluoroacetamides. J Am Chem Soc. 2014 Oct 15; 136(41):14401-4.
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      14. Bair JS, Schramm Y, Sergeev AG, Clot E, Eisenstein O, Hartwig JF. Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes. J Am Chem Soc. 2014 Sep 24; 136(38):13098-101.
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      15. Chen M, Hartwig JF. Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones. Angew Chem Int Ed Engl. 2014 Nov 3; 53(45):12172-6.
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      16. Green RA, Hartwig JF. Palladium-catalyzed amination of aryl chlorides and bromides with ammonium salts. Org Lett. 2014 Sep 5; 16(17):4388-91.
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      17. Cheng C, Hartwig JF. Mechanism of the rhodium-catalyzed silylation of arene C-h bonds. J Am Chem Soc. 2014 Aug 27; 136(34):12064-72.
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      18. Sevov CS, Hartwig JF. Iridium-catalyzed oxidative olefination of furans with unactivated alkenes. J Am Chem Soc. 2014 Jul 30; 136(30):10625-31.
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      19. Fier PS, Hartwig JF. Synthesis and Late-Stage Functionalization of Complex Molecules through C-H Fluorination and Nucleophilic Aromatic Substitution. J Am Chem Soc. 2014 Jul 16; 136(28):10139-47.
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      20. Li Q, Driess M, Hartwig JF. Iridium-catalyzed regioselective silylation of aromatic and benzylic c?h bonds directed by a secondary amine. Angew Chem Int Ed Engl. 2014 Aug 4; 53(32):8471-4.
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      21. Chen M, Hartwig JF. Iridium-Catalyzed Enantioselective Allylic Substitution of Unstabilized Enolates Derived from a,ß-Unsaturated Ketones. Angew Chem Int Ed Engl. 2014 Aug 11; 53(33):8691-5.
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      22. Li Q, Liskey CW, Hartwig JF. Regioselective borylation of the C-h bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-h bonds Beta to nitrogen and oxygen. J Am Chem Soc. 2014 Jun 18; 136(24):8755-65.
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      23. Li B, Driess M, Hartwig JF. Iridium-catalyzed regioselective silylation of secondary alkyl C-h bonds for the synthesis of 1,3-diols. J Am Chem Soc. 2014 May 7; 136(18):6586-9.
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      24. Mormino MG, Fier PS, Hartwig JF. Copper-Mediated Perfluoroalkylation of Heteroaryl Bromides with (phen)CuRF. Org Lett. 2014 Mar 21; 16(6):1744-7.
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      25. Ge S, Chaladaj W, Hartwig JF. Pd-Catalyzed a-Arylation of a,a-Difluoroketones with Aryl Bromides and Chlorides. A Route to Difluoromethylarenes. J Am Chem Soc. 2014 Mar 19; 136(11):4149-52.
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      26. Larsen MA, Hartwig JF. Iridium-catalyzed C-h borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism. J Am Chem Soc. 2014 Mar 19; 136(11):4287-99.
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      27. Cheng C, Hartwig JF. Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol. Science. 2014 Feb 21; 343(6173):853-7.
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      28. Sevov CS, Zhou JS, Hartwig JF. Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles. J Am Chem Soc. 2014 Feb 26; 136(8):3200-7.
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      29. Tran BL, Li B, Driess M, Hartwig JF. Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes. J Am Chem Soc. 2014 Feb 12; 136(6):2555-63.
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      30. Ge S, Green RA, Hartwig JF. Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex. J Am Chem Soc. 2014 Jan 29; 136(4):1617-27.
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      31. Denard CA, Huang H, Bartlett MJ, Lu L, Tan Y, Zhao H, Hartwig JF. Cooperative tandem catalysis by an organometallic complex and a metalloenzyme. Angew Chem Int Ed Engl. 2014 Jan 7; 53(2):465-9.
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      32. Chen W, Hartwig JF. Cation Control of Diastereoselectivity in Iridium-Catalyzed Allylic Substitutions. Formation of Enantioenriched Tertiary Alcohols and Thioethers by Allylation of 5H-Oxazol-4-ones and 5H-Thiazol-4-ones. J Am Chem Soc. 2014 Jan 8; 136(1):377-82.
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      33. Fier PS, Hartwig JF. Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction. Science. 2013 Nov 22; 342(6161):956-60.
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      34. Sharma A, Hartwig JF. Enantioselective functionalization of allylic C-h bonds following a strategy of functionalization and diversification. J Am Chem Soc. 2013 Nov 27; 135(47):17983-9.
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      35. Gallego D, Brück A, Irran E, Meier F, Kaupp M, Driess M, Hartwig JF. From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction. J Am Chem Soc. 2013 Oct 16; 135(41):15617-26.
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      36. Strom AE, Hartwig JF. One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination. J Org Chem. 2013 Sep 6; 78(17):8909-14.
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      37. Hama T, Ge S, Hartwig JF. Palladium-catalyzed a-arylation of zinc enolates of esters: reaction conditions and substrate scope. J Org Chem. 2013 Sep 6; 78(17):8250-66.
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      38. Cheng C, Simmons EM, Hartwig JF. Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8984-9.
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      39. Sevov CS, Hartwig JF. Iridium-catalyzed, intermolecular hydroetherification of unactivated aliphatic alkenes with phenols. J Am Chem Soc. 2013 Jun 26; 135(25):9303-6.
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      40. Shrestha R, Mukherjee P, Tan Y, Litman ZC, Hartwig JF. Sterically controlled, palladium-catalyzed intermolecular amination of arenes. J Am Chem Soc. 2013 Jun 12; 135(23):8480-3.
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      41. Cho SH, Hartwig JF. Iridium-catalyzed borylation of secondary benzylic C-h bonds directed by a hydrosilane. J Am Chem Soc. 2013 Jun 5; 135(22):8157-60.
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      42. Liskey CW, Hartwig JF. Iridium-catalyzed C-H borylation of cyclopropanes. J Am Chem Soc. 2013 Mar 6; 135(9):3375-8.
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      43. Fier PS, Luo J, Hartwig JF. Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex. J Am Chem Soc. 2013 Feb 20; 135(7):2552-9.
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      44. Sevov CS, Hartwig JF. Iridium-catalyzed intermolecular asymmetric hydroheteroarylation of bicycloalkenes. J Am Chem Soc. 2013 Feb 13; 135(6):2116-9.
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      45. Chen W, Hartwig JF. Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion. J Am Chem Soc. 2013 Feb 13; 135(6):2068-71.
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      46. Fier PS, Hartwig JF. Synthesis of difluoromethyl ethers with difluoromethyltriflate. Angew Chem Int Ed Engl. 2013 Feb 11; 52(7):2092-5.
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      47. Partridge BM, Hartwig JF. Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation. Org Lett. 2013 Jan 4; 15(1):140-3.
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      48. Sergeev AG, Webb JD, Hartwig JF. A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation. J Am Chem Soc. 2012 Dec 19; 134(50):20226-9.
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      49. Ge S, Hartwig JF. Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides. Angew Chem Int Ed Engl. 2012 Dec 14; 51(51):12837-41.
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      50. Chen W, Hartwig JF. Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. J Am Chem Soc. 2012 Sep 19; 134(37):15249-52.
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      51. Hanley PS, Marquard SL, Cundari TR, Hartwig JF. Reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes. J Am Chem Soc. 2012 Sep 19; 134(37):15281-4.
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      52. Liskey CW, Hartwig JF. Iridium-catalyzed borylation of secondary C-H bonds in cyclic ethers. J Am Chem Soc. 2012 Aug 1; 134(30):12422-5.
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      53. Sevov CS, Zhou J, Hartwig JF. Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides. J Am Chem Soc. 2012 Jul 25; 134(29):11960-3.
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      54. Fier PS, Hartwig JF. Copper-mediated fluorination of aryl iodides. J Am Chem Soc. 2012 Jul 4; 134(26):10795-8.
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      55. Madrahimov ST, Hartwig JF. Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes. J Am Chem Soc. 2012 May 16; 134(19):8136-47.
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      56. Fier PS, Hartwig JF. Copper-mediated difluoromethylation of aryl and vinyl iodides. J Am Chem Soc. 2012 Mar 28; 134(12):5524-7.
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      57. Klinkenberg JL, Hartwig JF. Reductive elimination from arylpalladium cyanide complexes. J Am Chem Soc. 2012 Apr 4; 134(13):5758-61.
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      58. Simmons EM, Hartwig JF. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes. Angew Chem Int Ed Engl. 2012 Mar 26; 51(13):3066-72.
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      59. Tan Y, Barrios-Landeros F, Hartwig JF. Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers. J Am Chem Soc. 2012 Feb 29; 134(8):3683-6.
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      60. Litvinas ND, Fier PS, Hartwig JF. A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]. Angew Chem Int Ed Engl. 2012 Jan 9; 51(2):536-9.
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      61. Hartwig JF. Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations. Acc Chem Res. 2012 Jun 19; 45(6):864-73.
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      62. Ge S, Hartwig JF. Nickel-catalyzed asymmetric a-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions. J Am Chem Soc. 2011 Oct 19; 133(41):16330-3.
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      63. Hanley PS, Hartwig JF. Intermolecular migratory insertion of unactivated olefins into palladium-nitrogen bonds. Steric and electronic effects on the rate of migratory insertion. J Am Chem Soc. 2011 Oct 5; 133(39):15661-73.
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      64. Sergeev AG, Hartwig JF. Selective, nickel-catalyzed hydrogenolysis of aryl ethers. Science. 2011 Apr 22; 332(6028):439-43.
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      65. Tan Y, Hartwig JF. Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species. J Am Chem Soc. 2011 Mar 16; 133(10):3308-11.
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      66. Liu Z, Yamamichi H, Madrahimov ST, Hartwig JF. Rhodium phosphine-p-arene intermediates in the hydroamination of alkenes. J Am Chem Soc. 2011 Mar 2; 133(8):2772-82.
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      67. Carrow BP, Hartwig JF. Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions. J Am Chem Soc. 2011 Feb 23; 133(7):2116-9.
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      68. Liao X, Stanley LM, Hartwig JF. Enantioselective total syntheses of (-)-taiwaniaquinone H and (-)-taiwaniaquinol B by iridium-catalyzed borylation and palladium-catalyzed asymmetric a-arylation. J Am Chem Soc. 2011 Feb 23; 133(7):2088-91.
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      69. Klinkenberg JL, Hartwig JF. Catalytic organometallic reactions of ammonia. Angew Chem Int Ed Engl. 2011 Jan 3; 50(1):86-95.
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      70. Simmons EM, Hartwig JF. Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation. J Am Chem Soc. 2010 Dec 8; 132(48):17092-5.
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      71. Giri R, Hartwig JF. Cu(I)-amido complexes in the Ullmann reaction: reactions of Cu(I)-amido complexes with iodoarenes with and without autocatalysis by CuI. J Am Chem Soc. 2010 Nov 17; 132(45):15860-3.
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      72. Julian LD, Hartwig JF. Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex. J Am Chem Soc. 2010 Oct 6; 132(39):13813-22.
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      73. Hartwig JF, Stanley LM. Mechanistically driven development of iridium catalysts for asymmetric allylic substitution. Acc Chem Res. 2010 Dec 21; 43(12):1461-75.
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      74. Klinkenberg JL, Hartwig JF. Slow reductive elimination from arylpalladium parent amido complexes. J Am Chem Soc. 2010 Sep 1; 132(34):11830-3.
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      75. Huang Z, Zhou JS, Hartwig JF. N-H activation of hydrazines by iridium(I). Double N-H activation to form iridium aminonitrene complexes. J Am Chem Soc. 2010 Aug 25; 132(33):11458-60.
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      76. Liskey CW, Liao X, Hartwig JF. Cyanation of arenes via iridium-catalyzed borylation. J Am Chem Soc. 2010 Aug 25; 132(33):11389-91.
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      77. Stanley LM, Bai C, Ueda M, Hartwig JF. Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates. J Am Chem Soc. 2010 Jul 7; 132(26):8918-20.
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      78. Hanley PS, Markovic D, Hartwig JF. Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate. J Am Chem Soc. 2010 May 12; 132(18):6302-3.
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      79. Robbins DW, Boebel TA, Hartwig JF. Iridium-catalyzed, silyl-directed borylation of nitrogen-containing heterocycles. J Am Chem Soc. 2010 Mar 31; 132(12):4068-9.
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      80. Tan Y, Hartwig JF. Palladium-catalyzed amination of aromatic C-H bonds with oxime esters. J Am Chem Soc. 2010 Mar 24; 132(11):3676-7.
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      81. Wei CS, Jiménez-Hoyos CA, Videa MF, Hartwig JF, Hall MB. Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes. J Am Chem Soc. 2010 Mar 10; 132(9):3078-91.
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      82. Sawyer KR, Cahoon JF, Shanoski JE, Glascoe EA, Kling MF, Schlegel JP, Zoerb MC, Hapke M, Hartwig JF, Webster CE, Harris CB. Time-resolved IR studies on the mechanism for the functionalization of primary C-H bonds by photoactivated Cp*W(CO)3(Bpin). J Am Chem Soc. 2010 Feb 17; 132(6):1848-59.
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      83. Carrow BP, Hartwig JF. Ligandless, anionic, arylpalladium halide intermediates in the Heck reaction. J Am Chem Soc. 2010 Jan 13; 132(1):79-81.
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      84. Ueda M, Hartwig JF. Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates. Org Lett. 2010 Jan 1; 12(1):92-4.
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      85. Tye JW, Hartwig JF. Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium. J Am Chem Soc. 2009 Oct 21; 131(41):14703-12.
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      86. Pouy MJ, Stanley LM, Hartwig JF. Enantioselective, iridium-catalyzed monoallylation of ammonia. J Am Chem Soc. 2009 Aug 19; 131(32):11312-3.
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      87. Vo GD, Hartwig JF. Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines. J Am Chem Soc. 2009 Aug 12; 131(31):11049-61.
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      88. Weix DJ, Markovic D, Ueda M, Hartwig JF. Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines. Org Lett. 2009 Jul 2; 11(13):2944-7.
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      89. Stanley LM, Hartwig JF. Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes. J Am Chem Soc. 2009 Jul 1; 131(25):8971-83.
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      90. Barrios-Landeros F, Carrow BP, Hartwig JF. Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes. J Am Chem Soc. 2009 Jun 17; 131(23):8141-54.
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      91. Alvaro E, Hartwig JF. Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium. J Am Chem Soc. 2009 Jun 10; 131(22):7858-68.
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      92. Madrahimov ST, Markovic D, Hartwig JF. The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions. J Am Chem Soc. 2009 Jun 3; 131(21):7228-9.
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      93. Stanley LM, Hartwig JF. Iridium-catalyzed regio- and enantioselective N-allylation of indoles. Angew Chem Int Ed Engl. 2009; 48(42):7841-4.
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      94. Hartwig JF. Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. Acc Chem Res. 2008 Nov 18; 41(11):1534-44.
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      95. Alexanian EJ, Hartwig JF. Mechanistic study of beta-hydrogen elimination from organoplatinum(II) enolate complexes. J Am Chem Soc. 2008 Nov 19; 130(46):15627-35.
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      96. Herzon SB, Hartwig JF. Hydroaminoalkylation of unactivated olefins with dialkylamines. J Am Chem Soc. 2008 Nov 12; 130(45):14940-1.
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      97. Ogata T, Hartwig JF. Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature. J Am Chem Soc. 2008 Oct 22; 130(42):13848-9.
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      98. Hartwig JF. Carbon-heteroatom bond formation catalysed by organometallic complexes. Nature. 2008 Sep 18; 455(7211):314-22.
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      99. Zhou JS, Hartwig JF. Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity. J Am Chem Soc. 2008 Sep 17; 130(37):12220-1.
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      100. Shen Q, Hartwig JF. [(CyPF-(t)Bu)PdCl2]: an air-stable, one-component, highly efficient catalyst for amination of heteroaryl and aryl halides. Org Lett. 2008 Sep 18; 10(18):4109-12.
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      101. Tye JW, Weng Z, Johns AM, Incarvito CD, Hartwig JF. Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides. J Am Chem Soc. 2008 Jul 30; 130(30):9971-83.
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      102. Boebel TA, Hartwig JF. Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes. J Am Chem Soc. 2008 Jun 18; 130(24):7534-5.
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      103. Shen Q, Ogata T, Hartwig JF. Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships. J Am Chem Soc. 2008 May 21; 130(20):6586-96.
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      104. Barrios-Landeros F, Carrow BP, Hartwig JF. Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br). J Am Chem Soc. 2008 May 7; 130(18):5842-3.
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      105. Liu Z, Hartwig JF. Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines. J Am Chem Soc. 2008 Feb 6; 130(5):1570-1.
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      106. Ueno S, Hartwig JF. Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols. Angew Chem Int Ed Engl. 2008; 47(10):1928-31.
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      107. Zhou J, Hartwig JF. Iridium-catalyzed H/D exchange at vinyl groups without olefin isomerization. Angew Chem Int Ed Engl. 2008; 47(31):5783-7.
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      108. Vo GD, Hartwig JF. Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. Angew Chem Int Ed Engl. 2008; 47(11):2127-30.
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      109. Liao X, Weng Z, Hartwig JF. Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel. J Am Chem Soc. 2008 Jan 9; 130(1):195-200.
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      110. Murphy JM, Liao X, Hartwig JF. Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation. J Am Chem Soc. 2007 Dec 19; 129(50):15434-5.
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      111. Markovic D, Hartwig JF. Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes. J Am Chem Soc. 2007 Sep 26; 129(38):11680-1.
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      112. Weix DJ, Hartwig JF. Regioselective and enantioselective iridium-catalyzed allylation of enamines. J Am Chem Soc. 2007 Jun 27; 129(25):7720-1.
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      113. Shen Q, Hartwig JF. Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides. J Am Chem Soc. 2007 Jun 27; 129(25):7734-5.
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      114. Yamashita Y, Gopalarathnam A, Hartwig JF. Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids. J Am Chem Soc. 2007 Jun 20; 129(24):7508-9.
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      115. Herzon SB, Hartwig JF. Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines. J Am Chem Soc. 2007 May 30; 129(21):6690-1.
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      116. Zhao P, Incarvito CD, Hartwig JF. Directly observed transmetalation from boron to rhodium. beta-aryl elimination from Rh(I) arylboronates and diarylborinates. J Am Chem Soc. 2007 Feb 21; 129(7):1876-7.
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      117. Johns AM, Liu Z, Hartwig JF. Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives. Angew Chem Int Ed Engl. 2007; 46(38):7259-61.
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      118. Johns AM, Tye JW, Hartwig JF. Relative rates for the amination of eta3-allyl and eta3-benzyl complexes of palladium. J Am Chem Soc. 2006 Dec 20; 128(50):16010-1.
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      119. Takemiya A, Hartwig JF. Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent. J Am Chem Soc. 2006 Nov 22; 128(46):14800-1.
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      120. Murphy JM, Lawrence JD, Kawamura K, Incarvito C, Hartwig JF. Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds. J Am Chem Soc. 2006 Oct 25; 128(42):13684-5.
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      121. Rosenfeld DC, Shekhar S, Takemiya A, Utsunomiya M, Hartwig JF. Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates. Org Lett. 2006 Sep 14; 8(19):4179-82.
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      122. Shekhar S, Trantow B, Leitner A, Hartwig JF. Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products. J Am Chem Soc. 2006 Sep 13; 128(36):11770-1.
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      123. Shen Q, Hartwig JF. Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides. J Am Chem Soc. 2006 Aug 9; 128(31):10028-9.
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      124. Zhao P, Incarvito CD, Hartwig JF. Carbon-oxygen bond formation between a terminal alkoxo ligand and a coordinated olefin. Evidence for olefin insertion into a rhodium alkoxide. J Am Chem Soc. 2006 Aug 2; 128(30):9642-3.
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      125. Johns AM, Sakai N, Ridder A, Hartwig JF. Direct measurement of the thermodynamics of vinylarene hydroamination. J Am Chem Soc. 2006 Jul 26; 128(29):9306-7.
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      126. Fujita K, Yamashita M, Puschmann F, Alvarez-Falcon MM, Incarvito CD, Hartwig JF. Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). J Am Chem Soc. 2006 Jul 19; 128(28):9044-5.
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      127. Sakai N, Ridder A, Hartwig JF. Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene. J Am Chem Soc. 2006 Jun 28; 128(25):8134-5.
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      128. Takemiya A, Hartwig JF. Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. J Am Chem Soc. 2006 May 10; 128(18):6042-3.
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      129. Hama T, Culkin DA, Hartwig JF. Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions. J Am Chem Soc. 2006 Apr 19; 128(15):4976-85.
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      130. Shekhar S, Ryberg P, Hartwig JF, Mathew JS, Blackmond DG, Strieter ER, Buchwald SL. Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. J Am Chem Soc. 2006 Mar 22; 128(11):3584-91.
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      131. Zhao P, Incarvito CD, Hartwig JF. Direct observation of beta-aryl eliminations from Rh(I) alkoxides. J Am Chem Soc. 2006 Mar 15; 128(10):3124-5.
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      132. Shekhar S, Ryberg P, Hartwig JF. Oxidative addition of phenyl bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for addition to Pd(BINAP). Org Lett. 2006 Mar 2; 8(5):851-4.
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      133. Fernández-Rodríguez MA, Shen Q, Hartwig JF. A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols. J Am Chem Soc. 2006 Feb 22; 128(7):2180-1.
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      134. Johns AM, Utsunomiya M, Incarvito CD, Hartwig JF. A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes. J Am Chem Soc. 2006 Feb 15; 128(6):1828-39.
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      135. Graening T, Hartwig JF. Iridium-catalyzed regio- and enantioselective allylation of ketone enolates. J Am Chem Soc. 2005 Dec 14; 127(49):17192-3.
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      136. Wu L, Hartwig JF. Mild palladium-catalyzed selective monoarylation of nitriles. J Am Chem Soc. 2005 Nov 16; 127(45):15824-32.
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      137. Leitner A, Shekhar S, Pouy MJ, Hartwig JF. A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis. J Am Chem Soc. 2005 Nov 9; 127(44):15506-14.
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      138. Boller TM, Murphy JM, Hapke M, Ishiyama T, Miyaura N, Hartwig JF. Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes. J Am Chem Soc. 2005 Oct 19; 127(41):14263-78.
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      139. Zhao P, Krug C, Hartwig JF. Transfer of amido groups from isolated rhodium(I) amides to alkenes and vinylarenes. J Am Chem Soc. 2005 Aug 31; 127(34):12066-73.
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      140. Zhao P, Hartwig JF. Beta-aryl eliminations from Rh(I) iminyl complexes. J Am Chem Soc. 2005 Aug 24; 127(33):11618-9.
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      141. Yan XZ, Pawlas J, Goodson T, Hartwig JF. Polaron delocalization in ladder macromolecular systems. J Am Chem Soc. 2005 Jun 29; 127(25):9105-16.
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      142. Barrios-Landeros F, Hartwig JF. Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands. J Am Chem Soc. 2005 May 18; 127(19):6944-5.
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      143. Takaya J, Hartwig JF. Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through pi-Arene Complexes. J Am Chem Soc. 2005 Apr 27; 127(16):5756-7.
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      144. Tsukada N, Hartwig JF. Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds. J Am Chem Soc. 2005 Apr 13; 127(14):5022-3.
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      145. Lee DY, Hartwig JF. Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates. Org Lett. 2005 Mar 17; 7(6):1169-72.
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      146. Hartwig JF, Cook KS, Hapke M, Incarvito CD, Fan Y, Webster CE, Hall MB. Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes. J Am Chem Soc. 2005 Mar 2; 127(8):2538-52.
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      147. Shen Q, Shekhar S, Stambuli JP, Hartwig JF. Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles. Angew Chem Int Ed Engl. 2005 Feb 18; 44(9):1371-5.
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      148. Bae C, Hartwig JF, Boaen Harris NK, Long RO, Anderson KS, Hillmyer MA. Catalytic hydroxylation of polypropylenes. J Am Chem Soc. 2005 Jan 19; 127(2):767-76.
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      149. Lawrence JD, Takahashi M, Bae C, Hartwig JF. Regiospecific functionalization of methyl C-H bonds of alkyl groups in reagents with heteroatom functionality. J Am Chem Soc. 2004 Dec 1; 126(47):15334-5.
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      150. Shekhar S, Hartwig JF. Distinct electronic effects on reductive eliminations of symmetrical and unsymmetrical bis-aryl platinum complexes. J Am Chem Soc. 2004 Oct 13; 126(40):13016-27.
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      151. Shu C, Hartwig JF. Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans. Angew Chem Int Ed Engl. 2004 Sep 13; 43(36):4794-7.
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      152. Shu C, Leitner A, Hartwig JF. Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst. Angew Chem Int Ed Engl. 2004 Sep 13; 43(36):4797-800.
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      153. Yamashita M, Hartwig JF. Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes. J Am Chem Soc. 2004 May 5; 126(17):5344-5.
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      154. Liu X, Hartwig JF. Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives. J Am Chem Soc. 2004 Apr 28; 126(16):5182-91.
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      155. Utsunomiya M, Hartwig JF. Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes. J Am Chem Soc. 2004 Mar 10; 126(9):2702-3.
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      156. Krug C, Hartwig JF. Imine insertion into a late metal-carbon bond to form a stable amido complex. J Am Chem Soc. 2004 Mar 10; 126(9):2694-5.
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      157. Stambuli JP, Incarvito CD, Bühl M, Hartwig JF. Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction. J Am Chem Soc. 2004 Feb 4; 126(4):1184-94.
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      158. Yamashita M, Cuevas Vicario JV, Hartwig JF. Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres. J Am Chem Soc. 2003 Dec 31; 125(52):16347-60.
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      159. Kiener CA, Shu C, Incarvito C, Hartwig JF. Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity. J Am Chem Soc. 2003 Nov 26; 125(47):14272-3.
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      160. Utsunomiya M, Hartwig JF. Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines. J Am Chem Soc. 2003 Nov 26; 125(47):14286-7.
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      161. Roy AH, Hartwig JF. Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes. J Am Chem Soc. 2003 Nov 19; 125(46):13944-5.
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      162. Kanzelberger M, Zhang X, Emge TJ, Goldman AS, Zhao J, Incarvito C, Hartwig JF. Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex. J Am Chem Soc. 2003 Nov 12; 125(45):13644-5.
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      163. Hama T, Liu X, Culkin DA, Hartwig JF. Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions. J Am Chem Soc. 2003 Sep 17; 125(37):11176-7.
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      164. Roy AH, Hartwig JF. Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature. J Am Chem Soc. 2003 Jul 23; 125(29):8704-5.
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      165. Stauffer SR, Hartwig JF. Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study. J Am Chem Soc. 2003 Jun 11; 125(23):6977-85.
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      166. Utsunomiya M, Kuwano R, Kawatsura M, Hartwig JF. Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes. J Am Chem Soc. 2003 May 14; 125(19):5608-9.
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      167. Hooper MW, Utsunomiya M, Hartwig JF. Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. J Org Chem. 2003 Apr 4; 68(7):2861-73.
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      168. López F, Ohmura T, Hartwig JF. Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides. J Am Chem Soc. 2003 Mar 26; 125(12):3426-7.
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      169. Webster CE, Fan Y, Hall MB, Kunz D, Hartwig JF. Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation. J Am Chem Soc. 2003 Jan 29; 125(4):858-9.
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      170. Ohmura T, Hartwig JF. Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. J Am Chem Soc. 2002 Dec 25; 124(51):15164-5.
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      171. Stambuli JP, Kuwano R, Hartwig JF. Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature. Angew Chem Int Ed Engl. 2002 Dec 16; 41(24):4746-8.
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      172. Jørgensen M, Lee S, Liu X, Wolkowski JP, Hartwig JF. Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates. J Am Chem Soc. 2002 Oct 23; 124(42):12557-65.
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      173. Culkin DA, Hartwig JF. Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles. J Am Chem Soc. 2002 Aug 14; 124(32):9330-1.
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      174. Stambuli JP, Bühl M, Hartwig JF. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J Am Chem Soc. 2002 Aug 14; 124(32):9346-7.
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      175. Ranasinghe MI, Varnavski OP, Pawlas J, Hauck SI, Louie J, Hartwig JF, Goodson T. Femtosecond excitation energy transport in triarylamine dendrimers. J Am Chem Soc. 2002 Jun 12; 124(23):6520-1.
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      176. Schlummer B, Hartwig JF. Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Org Lett. 2002 May 2; 4(9):1471-4.
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      177. Pawlas J, Nakao Y, Kawatsura M, Hartwig JF. A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism. J Am Chem Soc. 2002 Apr 10; 124(14):3669-79.
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      178. Krug C, Hartwig JF. Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. J Am Chem Soc. 2002 Feb 27; 124(8):1674-9.
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      179. Kondo Y, García-Cuadrado D, Hartwig JF, Boaen NK, Wagner NL, Hillmyer MA. Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. J Am Chem Soc. 2002 Feb 20; 124(7):1164-5.
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      180. Nettekoven U, Hartwig JF. A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. J Am Chem Soc. 2002 Feb 20; 124(7):1166-7.
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      181. Ishiyama T, Takagi J, Ishida K, Miyaura N, Anastasi NR, Hartwig JF. Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. J Am Chem Soc. 2002 Jan 23; 124(3):390-1.
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      182. Alcazar-Roman LM, Hartwig JF. Mechanism of aryl chloride amination: base-induced oxidative addition. J Am Chem Soc. 2001 Dec 26; 123(51):12905-6.
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      183. Chae HK, Eddaoudi M, Kim J, Hauck SI, Hartwig JF, O'Keeffe M, Yaghi OM. Tertiary building units: synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1). J Am Chem Soc. 2001 Nov 21; 123(46):11482-3.
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      184. Kawamura K, Hartwig JF. Isolated Ir(V) boryl complexes and their reactions with hydrocarbons. J Am Chem Soc. 2001 Aug 29; 123(34):8422-3.
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      185. Lee S, Beare NA, Hartwig JF. Palladium-catalyzed alpha-arylation of esters and protected amino acids. J Am Chem Soc. 2001 Aug 29; 123(34):8410-1.
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      186. Zhao J, Hesslink H, Hartwig JF. Mechanism of beta-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. J Am Chem Soc. 2001 Aug 1; 123(30):7220-7.
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      187. Culkin DA, Hartwig JF. C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. J Am Chem Soc. 2001 Jun 20; 123(24):5816-7.
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      188. Lee S, Hartwig JF. Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations. J Org Chem. 2001 May 18; 66(10):3402-15.
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      189. Stauffer SR, Beare NA, Stambuli JP, Hartwig JF. Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery. J Am Chem Soc. 2001 May 16; 123(19):4641-2.
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      190. Löber O, Kawatsura M, Hartwig JF. Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions. J Am Chem Soc. 2001 May 9; 123(18):4366-7.
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      191. Stambuli JP, Stauffer SR, Shaughnessy KH, Hartwig JF. Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions. J Am Chem Soc. 2001 Mar 21; 123(11):2677-8.
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      192. Roy AH, Hartwig JF. Reductive elimination of aryl halides from palladium(II). J Am Chem Soc. 2001 Feb 14; 123(6):1232-3.
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